938463-82-2Relevant academic research and scientific papers
Stereoselective difluoromethylenation using Me3SiCF 2SPh: Synthesis of chiral 2,4-disubstituted 3,3-difluoropyrrolidines
Li, Ya,Hu, Jinbo
, p. 2489 - 2492 (2007)
A radical synthon: Nucleophilic (phenylthio)difluoromethylation of (R)-N-(tert-butylsulfinyl)imines with 1, a difluoromethylene radical anion equivalent, afforded the corresponding products in good yields and with high diastereoselectivity (d.r. ≥ 98:2).
Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te)
Hu, Mingyou,Wang, Fei,Zhao, Yanchuan,He, Zhengbiao,Zhang, Wei,Hu, Jinbo
experimental part, p. 45 - 58 (2012/03/27)
A series of sulfur-, selenium- and tellurium-containing (phenylchalcogen)difluoromethylation reagents PhSCF2H (1a), PhSeCF2H (1b), and PhTeCF2H (1c) were prepared, and their relative reactivity towards aldehydes, ketones,
