939017-92-2Relevant academic research and scientific papers
Enzyme-Catalyzed Intramolecular Enantioselective Hydroalkoxylation
Gao, Shu-Shan,Garcia-Borràs, Marc,Barber, Joyann S.,Hai, Yang,Duan, Abing,Garg, Neil K.,Houk,Tang, Yi
, p. 3639 - 3642 (2017)
Hydroalkoxylation is a powerful and efficient method of forming C-O bonds and cyclic ethers in synthetic chemistry. In studying the biosynthesis of the fungal natural product herqueinone, we identified an enzyme that can perform an intramolecular enantios
Stereoselective syntheses of the 2-isopropenyl-2,3-dihydrobenzofuran nucleus: Potential chiral building blocks for the syntheses of tremetone, hydroxytremetone, and rotenone
Pelly, Stephen C.,Govender, Sameshnee,Fernandes, Manuel A.,Schmalz, Hans-Guenther,De Koning, Charles B.
, p. 2857 - 2864 (2008/02/01)
(Chemical Equation Presented) The first enantioselective synthesis of the 2-isopropenyl-2,3-dihydrobenzofuran skeleton of tremetone and hydroxytremetone from (E)-4-(2-hydroxyphenyl)-2-methyl-2-butenyl methyl carbonate and (E)-4-(2,6-dihydroxyphenyl)-2-met
