93972-01-1Relevant articles and documents
Iron-catalyzed cross-coupling reaction of alkyl halides with biphenyl grignard reagent
Dai,Liu,Zhang,Wei,Guan
, p. 6303 - 6305 (2013/07/26)
In the presence of a catalytic amount of iron salts and N,N,N',N'-tetramethylethylene diamine as additive, alkyl bromide reacted with biphenyl magnesium bromide to obtain the cross-coupling product in good yields. The suitable amount of catalyst and the additive are 5 % mol (based on alkyl bromide), 1.3 equiv(based on alkyl bromide), respectively. Under the optimal conditions, the yields of the crosscoupling could reach up to 92.3 %.