940006-60-0Relevant articles and documents
l-Rhamnosylation: The Solvent is the Solution
Elferink, Hidde,Pedersen, Christian Marcus
, p. 53 - 59 (2017/01/14)
Herein we present a systematic study of l-rhamnosylation. The influence of protective groups, reactivity, solvents and glycosylation method, i.e. catalytic versus promoted glycosylation, are studied. It was found that the selectivity can be controlled to
Synthesis of all eight stereoisomeric 6-deoxy-l-hexopyranosyl donors - Trends in using stereoselective reductions or mitsunobu epimerizations
Frihed, Tobias Gylling,Pedersen, Christian Marcus,Bols, Mikael
, p. 7924 - 7939 (2015/02/18)
The synthesis of all eight rare but biologically important 6deoxy-L-hexoses as their thioglycoside glycosyl donors starting from the commercially available L-rhamnose or L-fucose is reported. The synthesis of all eight 6-deoxy-L-hexoses was accomplished u
Facile oxidative cleavage of 4-O-benzyl ethers with dichlorodicyanoquinone in rhamno- and mannopyranosides
Crich, David,Vinogradova, Olga
, p. 3581 - 3584 (2008/02/04)
On exposure to dichlorodicyanoquinone in wet dichloromethane at room temperature, equatorial 4-O-benzyl ethers are removed with moderate selectivity in the presence of other benzyl ethers in glycopyranosides and glycothiopyranosides.