940006-52-0

Basic information

• Product Name: S-phenyl 3-O-benzyl-α-L-thiorhamnopyranoside
• Synonyms: S-phenyl 3-O-benzyl-α-L-thiorhamnopyranoside
• CAS NO: 940006-52-0
• Molecular Weight: 346.447
• Mol File: 940006-52-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: S-phenyl 3-O-benzyl-α-L-thiorhamnopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: S-phenyl 3-O-benzyl-α-L-thiorhamnopyranoside(940006-52-0)
• EPA Substance Registry System: S-phenyl 3-O-benzyl-α-L-thiorhamnopyranoside(940006-52-0)

Safety Data

• Hazardous Substances Data: 940006-52-0(Hazardous Substances Data)

Upstream product

• 940006-58-6 S-phenyl 2-O-acetyl-4-O-benzyl-3-O-(4-methoxybenzyl)-α-L-thiorhamnopyranoside 
• 940006-60-0 phenyl 2,3-O-isopropylidene-4-O-(2-naphthylmethyl)-1-thio-α-L-rhamnopyranoside 
• 172296-66-1 Phenyl 3,4-di-O-benzyl-1-thio-α-L-rhamnopyranoside 
• 1214-98-8 phenyl 1-thio-α-L-rhamnopyranose 
• 100-44-7 benzyl chloride 
• 146399-74-8 phenyl 4-O-benzyl-1-thio-α-L-rhamnopyranoside 
• 131087-35-9 phenyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside 
• 100-39-0 benzyl bromide 
• 131897-04-6 phenyl 2,3,4-tri-O-benzyl-1-thio-α-L-rhamnopyranoside 
• 940006-61-1 phenyl 2,3-di-O-benzyl-4-O-(2-naphthylmethyl)-1-thio-α-L-rhamnopyranoside 

Downstream Products

• 1046465-35-3 phenyl 6-deoxy-3-O-benzyl-2-O-pivaloyl-1-thio-α-L-rhamnopyranose 

Relevant articles and documents

Synthesis of a tetrasaccharide phosphate from the linkage region of the arabinogalactan-peptidoglycan complex in the mycobacterial cell wall

The synthesis of dibenzyl 6-O-naphthylmethyl-2,3,5-tri-O-benzoyl-β-d-galactofuranosyl-(1→5)-2,3-di-O-benzoyl-6-O-benzyl-β-d-galactofuranosyl-(1→4)-3-O-benzyl-2-O-pivaloyl-α-l-rhamnopyranosyl-(1→3)-2-acetamido-2-deoxy-4,6-di-O-benzoyl-α-d-glucopyranosyl phosphate (1), a protected form of the tetrasaccharide phosphate of the linkage region of the arabinogalactan-peptidoglycan complex in the mycobacterial cell wall, has been accomplished. Key steps include the coupling of four monosaccharide building blocks with complete stereoselectivity by glycosylations employing thioglycosides, 2′-carboxybenzyl glycosides, and glycosyl fluorides as glycosyl donors. The α-glycosyl phosphate linkage was also stereoselectively elaborated by reaction of a tetrasaccharide hemiacetal with tetrabenzyl pyrophosphate in the presence of a base.