94001-91-9Relevant academic research and scientific papers
Neighboring lithium-assisted [1,2]-wittig rearrangement: Practical access to diarylmethanol-based 1,4-diols and optically active binol derivatives with axial and sp3-central chirality
Gao, Guang,Gua, Feng-Lei,Jiang, Jian-Xiong,Jiang, Kezhi,Sheng, Chun-Qi,Lai, Guo-Qiao,Xu, Li-Wen
, p. 2698 - 2703 (2011/04/15)
A facile and practical methodology for the synthesis of synthetically useful diarylmethanol-based 1,4-diols and enantiomerically pure BINOL-derived diols with axial and sp3-central chirality has been developed through neighboring lithium-promot
4,5 Dihydroimidazole compounds which have useful pharmaceutical utility
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, (2008/06/13)
A compound of formula (I): STR1 or a pharmaceutically acceptable salt, ester or amide thereof, or a pharmaceutically acceptable solvate thereof, wherein: Z represents a residue of a substituted or unsubstituted aryl group, A1 represents a subst
Reactions of Trialkylborane. VI. Reduction of Carbonyl Compounds with Trialkylborane
Nose, Atsuko,Kudo, Tadahiro
, p. 4335 - 4339 (2007/10/02)
The reduction of anhydrides, lactones, esters, carboxylic acids and acyl chlorides with trialkylborane is described.Cyclic anhydrides were reduced with 4 mol eq of trialkylborane at temperatures above 300 deg C to give diol derivatives via the lactones.Lactones, esters, carboxylic acids and acyl chlorides were reduced under similar conditions to give the corresponding alcohol derivatives.Keywords-reduction; trialkylborane; anhydride; lactone; ester; carboxylic acid; alcohol; carbonyl compound
