940296-63-9Relevant academic research and scientific papers
Dipalladium complex with bridging silylene ligands, {Pd(dmpe)} 2(μ-SiPh2)2L formed via dimerization of a bis(silyl)paliadium complex
Tanabe, Makoto,Mawatari, Akane,Osakada, Kohtaro
, p. 2937 - 2940 (2007)
Heating a toluene solution of the bis(silyl)palladium complex [Pd(SiHPh2)2(dmpe)] (1) (dmpe = 1,2-bis(dimethylphosphino) ethane) at 60°C afforded a dipalladium complex with bridging silylene ligands, [{Pd(dmpe)}2(μ-SiPh2)2] (2), accompanied by H2SiPh2 elimination. An X-ray crystallographic study of 2 suggested the presence of a Si...Si interaction in the four-membered Pd2Si2 ring.
