94040-95-6

Basic information

• Product Name: Benzene, 1-azido-4-(phenylmethoxy)-
• CAS NO: 94040-95-6
• Molecular Formula: C13H11N3O
• Molecular Weight: 225.25
• Mol File: 94040-95-6.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, 1-azido-4-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-azido-4-(phenylmethoxy)-(94040-95-6)
• EPA Substance Registry System: Benzene, 1-azido-4-(phenylmethoxy)-(94040-95-6)

Safety Data

• Hazardous Substances Data: 94040-95-6(Hazardous Substances Data)

Upstream product

• 81499-31-2 C₁₄H₁₄O₃S 
• 51388-20-6 4-benzyloxyaniline hydrochloride 
• 6373-46-2 p-benzyloxyaniline 
• 146631-00-7 [4-(benzyloxy)phenyl]boronic acid 
• 123-30-8 4-amino-phenol 
• 24541-43-3 4-azidophenol 
• 100-39-0 benzyl bromide 

Downstream Products

• 947271-53-6 1-[4-(benzyloxy)phenyl]-5-phenyl-1H-1,2,3-triazole-4-carboxylic acid 
• 6373-46-2 p-benzyloxyaniline 
• 1391092-32-2 4-ferrocenyl-1-(4-benzyloxyphenyl)-1H-1,2,3-triazole 

Relevant articles and documents

Nickel Boride Catalyzed Reductions of Nitro Compounds and Azides: Nanocellulose-Supported Catalysts in Tandem Reactions

Nickel boride catalyst prepared in situ from NiCl2 and sodium borohydride allowed, in the presence of an aqueous solution of TEMPO-oxidized nanocellulose (0.01 wt%), the reduction of a wide range of nitroarenes and aliphatic nitro compounds. Here we describe how the modified nanocellulose has a stabilizing effect on the catalyst that enables low loading of the nickel salt pre-catalyst. Ni-B prepared in situ from a methanolic solution was also used to develop a greener and facile reduction of organic azides, offering a substantially lowered catalyst loading with respect to reported methods in the literature. Both aromatic and aliphatic azides were reduced, and the protocol is compatible with a one-pot Boc-protection of the obtained amine yielding the corresponding carbamates. Finally, bacterial crystalline nanocellulose was chosen as a support for the Ni-B catalyst to allow an easy recovery step of the catalyst and its recyclability for new reduction cycles.

Synthesis, antibacterial, and antioxidant activities of naphthyl-linked disubstituted 1,2,3-triazoles

Here, click synthesis of 15 naphthyl-linked disubstituted 1,2,3-triazoles has been carried out by the reaction between 1-(prop-2-yn-1-yloxy)naphthalene and aromatic azides. The structure elucidation of the synthesized compounds was carried out by FTIR, s

INHIBITORS OF INDOLEAMINE 2,3-DIOXYGENASE AND/OR TRYPTOPHAN 2,3-DIOXYGENASE

The present invention relates to compounds of Formula (I) inhibiting indoleamine 2,3-dioxygenase (IDO) and/or tryptophan 2,3-dioxygenase (TDO) enzymes. Further, their synthesis and their use as medicaments in inter alia the treatment of cancer is disclosed. Formula (I)