94096-08-9

Basic information

• Product Name: 4-Ethoxycarbonyl-phenylthiocyanat
• Synonyms: 4-Ethoxycarbonyl-phenylthiocyanat
• CAS NO: 94096-08-9
• Molecular Weight: 207.253
• Mol File: 94096-08-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Ethoxycarbonyl-phenylthiocyanat(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Ethoxycarbonyl-phenylthiocyanat(94096-08-9)
• EPA Substance Registry System: 4-Ethoxycarbonyl-phenylthiocyanat(94096-08-9)

Safety Data

• Hazardous Substances Data: 94096-08-9(Hazardous Substances Data)

Upstream product

• 1111-67-7 copper(I) thiocyanate 
• 94-09-7 p-aminoethylbenzoate 
• 540-72-7 sodium thiocyanide 
• 348-06-1 p-carboethoxybenzenediazonium tetrafluoroborate 

Relevant articles and documents

One-pot synthesis of (ethoxycarbonyl)difluoromethylthioethers from thiocyanate sodium and ethyl 2-(trimethylsilyl)-2,2-difluoroacetate (TMS-CF2CO2Et)

An efficient one-pot cascade methodology for the synthesis of (ethoxycarbonyl)difluoromethyl thioethers is described. Benzyl, allyl, alkyl halides or diazonium salts as the starting materials together with thiocyanate sodium and TMS-CF2CO2Et in the presence of CsF or NaOAc afford a variety of the fluoroalkylthiolated products in moderate to good yields.