94100-70-6Relevant academic research and scientific papers
Synthesis and Absolute Configuration of Optically Active E-1-Alkoxymethoxybut-2-enyl(tri-n-butyl)stannanes: Stereoselective Reactions with Aldehydes
Jephcote, Vincent J.,Pratt, Andrew J.,Thomas, Eric J.
, p. 800 - 802 (2007/10/02)
(1R)- and (1S)-1--E-but-2-enyl(tri-n-butyl)stannanes (5) and (6), whose configurations at C(1) were assigned by correlation with (2R)- and (2S)-pentan-2-ol, react stereoselectively on heating with benzaldehyde to give (3S,4S)- and (3R,4R)-4-hydroxy-3-methyl-cis-1,2-enol ethers (11) and (13), respectively.
