94102-28-0Relevant academic research and scientific papers
Catalyst-free chemoselective α-sulfenylation/β-thiolation for α,β-unsaturated carbonyl compounds
Huang, Xi,Li, Juan,Li, Xiang,Wang, Jiayi,Peng, Yanqing,Song, Gonghua
, p. 26419 - 26424 (2019/09/13)
A novel, efficient, catalyst-free and product-controllable strategy has been developed for the chemoselective α-sulfenylation/β-thiolation of α,β-unsaturated carbonyl compounds. An aromatic sulfur group could be chemoselectively introduced at α-or β-posit
One-pot stereoselective synthesis of (z)α-arylthioα-,- unsaturated ketones by hydrostannylation-stille tandem reaction of acetylenic sulfides
You, Shengyong,Hao, Wenyan,Cai, Mingzhong
experimental part, p. 1830 - 1836 (2010/07/05)
(Z)αβ-Arylthioα-βunsaturated ketones can be stereoselectively synthesized in one pot under mild conditions, in good yields, by the palladium-catalyzed hydrostannylation of acetylenic sulfides with tributyltin hydride, followed by Stille coupling with acyl
A novel stereoselective synthesis of (z)-α-arylsulfanyl-α, β-unsaturated ketones via stille coupling of (E)-α- Arylsulfanylvinylstannanes with acyl halides
Yao, Fang,You, Shengyong,Cai, Mingzhong
experimental part, p. 218 - 223 (2010/01/18)
(E)-α-Arylsulfanylvinylstannanes react with acyl halides in the presence of a catalytic amount of Pd(PPh3)4 and CuI cocatalyst to give stereoselectively the corresponding (Z)-α-arylsulfanyl- α,β-unsaturated ketones in good yields.
