94113-07-2

Basic information

• Product Name: Ethanone, 1,1'-[1,1'-biphenyl]-3,3'-diylbis-
• CAS NO: 94113-07-2
• Molecular Formula: C16H14O2
• Molecular Weight: 238.286
• Mol File: 94113-07-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Ethanone, 1,1'-[1,1'-biphenyl]-3,3'-diylbis-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1,1'-[1,1'-biphenyl]-3,3'-diylbis-(94113-07-2)
• EPA Substance Registry System: Ethanone, 1,1'-[1,1'-biphenyl]-3,3'-diylbis-(94113-07-2)

Safety Data

• Hazardous Substances Data: 94113-07-2(Hazardous Substances Data)

Upstream product

• 2142-63-4 1-(3-Bromophenyl)ethanone 
• 10365-98-7 3-methoxyphenylboronic acid 
• 540-49-8 cis+trans-dibromoethylene 
• 1722-10-7 3-chloro-6-methoxypyridazine 
• 1663-39-4 tert-Butyl acrylate 
• 529-28-2 4-iodoanisol 
• 443777-09-1 1-(3-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)phenyl)ethanone 

Downstream Products

• 159389-27-2 3,3'-Bis<4-(methylsulfanyl)-2,2'-bipyridin-6-yl>biphenyl 
• 1401538-27-9 C₃₀H₂₂O₄ 

Relevant articles and documents

Rhodium-catalyzed cross-coupling of alkenyl halides with arylboron compounds

The rhodium(I)-catalyzed reaction between arylboronic esters and excess 1,2-dichloroethene selectively afforded (2-chlorovinyl)arenes. Double arylation yielding 1,2-diarylethenes was observed when 1,2-dibromoethene was reacted with 2.5 equivalents of aryl

Preparation of functionalized aryl- and heteroarylpyridazines by nickel-catalyzed electrochemical cross-coupling reactions

(Chemical Equation Presented) A general efficient electrochemical method for the preparation of aryl- and heteroarylpyridazines in a nickel-catalyzed cross-coupling reaction of 3-chloro-6-methoxypyridazine and 3-chloro-6- methylpyridazine with a range of functionalized aryl or heteroaryl halides is reported.

Palladium-catalyzed cross-coupling of bromobenzenes, containing an acetyl or a formyl group, with organozinc reagents

The reaction of organozinc halides RZnX (R=Bu, Ph; X=Cl, Br) with m- and p-bromoacetophenones in the presence of PdCl2(PPh3)2 in THF/HMPA (THF=tetrahydrofuran; HMPA=N,N,N',N',N'',N''-hexamethylphosphoric triamide) takes place chemoselectively to give the corresponding m- and p-R-substituted acetophenones in high yields.Similarly reaction of RZnX with p-bromobenzaldehyde also proceeds chemoselectively to give the p-R-substituted benzaldehyde in good yields.