94124-50-2Relevant academic research and scientific papers
PALLADIUM-CATALYZED PREPARATION OF α-ALLYL ESTERS AND α,β-UNSATURATED ESTERS FROM SATURATED ESTERS VIA THEIR KETENE SILYL ACETALS
Tsuji, Jiro,Takahashi, Kazuhiro,Minami, Ichiro,Shimizu, Isao
, p. 4783 - 4786 (1984)
Reaction of ketene silyl acetals with allylic carbonates in the presence of palladium-phosphine catalyst in dioxane gives α-allyl esters in high yields.When the reaction is carried out with phosphine-free palladium catalyst in nitriles, α,β-unsaturated esters are obtained in good yields.
