Tetrahedron Letters p. 4783 - 4786 (1984)
Update date:2022-08-04
Topics:
Tsuji, Jiro
Takahashi, Kazuhiro
Minami, Ichiro
Shimizu, Isao
Reaction of ketene silyl acetals with allylic carbonates in the presence of palladium-phosphine catalyst in dioxane gives α-allyl esters in high yields.When the reaction is carried out with phosphine-free palladium catalyst in nitriles, α,β-unsaturated esters are obtained in good yields.
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