941305-82-4

Basic information

• Product Name: 1-bromomethyl-4-methoxy-2-vinyl-benzene
• Synonyms: 1-bromomethyl-4-methoxy-2-vinyl-benzene
• CAS NO: 941305-82-4
• Molecular Weight: 227.101
• Mol File: 941305-82-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-bromomethyl-4-methoxy-2-vinyl-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromomethyl-4-methoxy-2-vinyl-benzene(941305-82-4)
• EPA Substance Registry System: 1-bromomethyl-4-methoxy-2-vinyl-benzene(941305-82-4)

Safety Data

• Hazardous Substances Data: 941305-82-4(Hazardous Substances Data)

Upstream product

• 43192-31-0 2-bromo-4-methoxybenzaldehyde 

Downstream Products

• 1019984-10-1 2-(4-methoxy-phenyl)-3-(4-methoxy-2-vinyl-phenyl)-propionic acid methyl ester 

Relevant articles and documents

Enantioselective Copper-Catalyzed Desymmetrization of 1,3-Diketones Involving Borylation of Styrenes

A copper-catalyzed intramolecular enantioselective and diastereoselective borylative coupling of styrenes and ketones was achieved by merging desymmetrization strategy and olefin difunctionalization. The reaction proceeds through an initial enantioselective borylcupration of styrenes, followed by a highly selective direct addition to 1,3-diketones. The bicyclic scaffolds with three chiral carbon centers, including two tetrasubstituted carbons, were generated in excellent yields, diastereoselectivities, and enantioselectivities. This catalytic tandem reaction has great potential for further synthetic application of the chiral polycyclic compounds, because of the versatility of the functional groups in the products.