94134-32-4

Usage

InChI:InChI=1/C15H22O2/c1-5-6-11-17-14(16)12-7-9-13(10-8-12)15(2,3)4/h7-10H,5-6,11H2,1-4H3

Upstream product

• 60561-82-2 1-(4-(tert-butyl)phenyl)-2-methylpropan-1-one 
• 26501-54-2 tetrabutylammonium nitrite 
• 201230-82-2 carbon monoxide 
• 160788-98-7 4-(tert-butyl)phenyl benzenesulfonate 
• 71-36-3 butan-1-ol 
• 59970-38-6 4-tert-butylphenyl mesylate 
• 7598-28-9 4-tert-butylphenyltosylate 
• 145142-71-8 N-(acetoxy)-butoxy-4-(tert-butul)benzamide 
• 100-61-8 N-methylaniline 
• 109-65-9 1-bromo-butane 

Relevant academic research and scientific papers

Copper-catalyzed synthesis of esters from ketones. Alkyl group as a leaving group

The conversion of ketones to esters has been achieved through the use of Cu catalyst and tetrabutylammonium nitrite. This reaction involves the activation of the less activated C-C bond, and the alkyl group is removed as a leaving group. Various isopropyl ketones are found to be good substrates for this reaction.

Palladium-catalyzed carbonylation of aryl tosylates and mesylates

A general protocol for the palladium-catalyzed carbonylation of aryl tosylates and mesylates to form esters has been developed using a catalyst system derived from Pd(OAc)2 and the bulky, bidentate dcpp ligand. The system operates under mild conditions: atmospheric CO pressure and temperatures of 80-110 °C. A broad substrate scope has been demonstrated allowing carbonylation of electron-rich, electron-poor, and heterocyclic tosylates and mesylates, and the reaction shows wide functional group tolerance. Copyright

Bimolecular Reactions of Mutagenic N-Acetoxy-N-alkoxybenzamides and N-Methylaniline

N-Methylaniline reacts bimolecularly with mutagenic N-acetoxy-N-alkoxybenzamides and the resultant N-alkoxy-N-(N-methylanilino)benzamides undergo a novel, concerted rearrangement to alkylbenzoates and 1-methyl-1-phenyldiazene which dimerizes to 1,4-dimethyl-1,4-diphenyl-tetrazene.

The Influence of Water Traces on Some Liquid/Solid Phase Transfer Catalysis Processes (Applications of Phase Transfer Catalysis, Part 42)

Rates of solid/liquid phase transfer catalytic conversions (an ester formation, an ether formation, a cyanide displacement, and a dichlorocarbene generation) were investigated using onium salts and dicyclohexano-18-crown-6 as catalysts and varying the (very low) water content of the system.The influence of the water traces varies strongly with the types of anions and catalysts.