94152-31-5Relevant academic research and scientific papers
An α-Diazoalkylosmium Complex as a Carbyne-complex Precursor. Synthesis and X-Ray Crystal Structure of HCO2Et)(PPh3)>, the Product of an Intramolecular Carbyne Insertion Reaction
Gallop, Mark A.,Jones, Tony C.,Rickard, Clifton E. F.,Roper, Warren R.
, p. 1002 - 1003 (1984)
The α-diazoalkylosmium complex loses N2 to give the title complex and the formation of this metallacyclic compound, which has been structurally characterised by single crystal X-ray diffraction, is interpreted as arising from an intramolecular insertion reaction of an intermediate cationic carbyne complex, I.
