An α-Diazoalkylosmium Complex as a Carbyne-complex Precursor. Synthesis and X-Ray Crystal Structure of HCO2Et)(PPh3)>, the Product of an Intramolecular Carbyne Insertion Reaction

DOI: 10.1039/c39840001002

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1002 - 1003 (1984)

Update date:2022-08-16

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Authors:

Gallop, Mark A.

Jones, Tony C.

Rickard, Clifton E. F.

Roper, Warren R.

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Article abstract of DOI:10.1039/c39840001002

The α-diazoalkylosmium complex loses N2 to give the title complex and the formation of this metallacyclic compound, which has been structurally characterised by single crystal X-ray diffraction, is interpreted as arising from an intramolecular insertion reaction of an intermediate cationic carbyne complex, I.

Full text of DOI:10.1039/c39840001002

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Product name:OsCl(NO)(P(C₆H₅)3)2Hg(CN₂CO₂C₂H₅)(CN₂CO₂C₂H₅)

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