94160-13-1Relevant academic research and scientific papers
Method for synthesizing 1,9-decadiene
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Paragraph 0050-0052, (2019/07/01)
The invention discloses a method for synthesizing 1,9-decadiene. The method sequentially comprises the following steps: adding carboxylic acid and 1,10-decadienol into a reaction container, heating the container until the 1,10-decadienol is dissolved, adding a catalyst, carrying out an esterification reaction at 120-200 DEG C, and collecting water evaporated in the esterification reaction; continuously heating the container to 300-350 DEG C after no water is produced in the esterification reaction, carrying out a reaction for 5-8 h, and evaporating and collecting a mixed solution of 1,9-decadiene and carboxylic acid; and respectively post-processing the mixed of 1,9-decadiene and carboxylic acid to obtain carboxylic acid and 1,9-decadiene respectively. The method for preparing 1,9-decadiene is efficient, economical and green, and meets industrial production requirements.
Nickel-Catalyzed reductive cross-Coupling of unactivated alkyl halides
Yu, Xiaolong,Yang, Tao,Wang, Shulin,Xu, Hailiang,Gong, Hegui
supporting information; experimental part, p. 2138 - 2141 (2011/06/22)
A Ni-catalyzed reductive approach to the cross-coupling of two unactivated alkyl halides has been successfully developed. The reaction works efficiently for primary and secondary halides, with at least one being bromide. The mild reaction conditions allow for excellent functional group tolerance and provide the C(sp3)-C(sp3) coupling products in moderate to excellent yields.
