942147-72-0Relevant academic research and scientific papers
Thermal Dehydrogenation and Hydrolysis of BH3NH3Catalyzed by Cyclic (Alkyl)(amino)carbene Iridium Complexes under Mild Conditions
Zhou, Lei,Zhang, Dejin,Hu, Jinling,Wu, Youting,Geng, Jiao,Hu, Xingbang
, p. 2643 - 2650 (2021/08/03)
Though ammonia-borane (AB) is recognized as an excellent hydrogen storage material, efficient dehydrogenation of AB still remains a challenge. Herein, we report that cyclic (alkyl)(amino)carbene iridium complexes are highly efficient for both the thermal
PREPARATION OF PRECURSORS OF CARBENES OF CAAC TYPE AND PREPARING SAID CARBENES THEREFROM
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Page/Page column 16, (2010/05/13)
Precursors of carbenes of CAAC type (Cyclic)(Alkyl)(Amino)(Carbenes) are prepared and carbenes are produced therefrom; novel synthesis intermediates are provided for preparing the precursors of CAAC-type carbenes.
Intramolecular "hydroiminiumation" of alkenes: Application to the synthesis of conjugate acids of Cyclic Alkyl Amino Carbenes (CAACs)
Jazzar, Rodolphe,Dewhurst, Rian D.,Bourg, Jean-Baptiste,Donnadieu, Bruno,Canac, Yves,Bertrand, Guy
, p. 2899 - 2902 (2008/02/12)
(Chemical Equation Presented) A rival for the hydroamination reaction: The intramolecular "hydroiminiumation" reaction features some distinct advantages over intramolecular hydroamination since the resulting prochiral iminium ions potentially allow the su
