869085-71-2Relevant academic research and scientific papers
Intramolecular "hydroiminiumation" of alkenes: Application to the synthesis of conjugate acids of Cyclic Alkyl Amino Carbenes (CAACs)
Jazzar, Rodolphe,Dewhurst, Rian D.,Bourg, Jean-Baptiste,Donnadieu, Bruno,Canac, Yves,Bertrand, Guy
, p. 2899 - 2902 (2007)
(Chemical Equation Presented) A rival for the hydroamination reaction: The intramolecular "hydroiminiumation" reaction features some distinct advantages over intramolecular hydroamination since the resulting prochiral iminium ions potentially allow the su
Thermal Dehydrogenation and Hydrolysis of BH3NH3Catalyzed by Cyclic (Alkyl)(amino)carbene Iridium Complexes under Mild Conditions
Zhou, Lei,Zhang, Dejin,Hu, Jinling,Wu, Youting,Geng, Jiao,Hu, Xingbang
, p. 2643 - 2650 (2021)
Though ammonia-borane (AB) is recognized as an excellent hydrogen storage material, efficient dehydrogenation of AB still remains a challenge. Herein, we report that cyclic (alkyl)(amino)carbene iridium complexes are highly efficient for both the thermal
Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes
Weinstein, Cory M.,Junor, Glen P.,Tolentino, Daniel R.,Jazzar, Rodolphe,Melaimi, Mohand,Bertrand, Guy
supporting information, p. 9255 - 9260 (2018/07/09)
Cyclic (alkyl)(amino)carbenes with a six-membered backbone were prepared. Compared to their five-membered analogues, they feature increased %Vbur and enhanced donor and acceptor properties, as evidenced by the observed n → π? transition trailin
Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: A quaternary carbon atom makes the difference
Lavallo, Vincent,Canac, Yves,Praesang, Carsten,Donnadieu, Bruno,Bertrand, Guy
, p. 5705 - 5709 (2007/10/03)
(Chemical Equation Presented) Like NHCs? Not quite: Cyclic (alkyl)-(amino)carbenes (CAACs) are strong σ-donors and have steric environments that differ dramatically from those of bulky, electron-rich phosphines (A) and cyclic diaminocarbenes (B). These re
