942202-92-8

Basic information

• Product Name: 3-(4-(6-(tert-butyldiphenylsilyl-oxy)-2-hydroxy-2-methylhexyl)-phenoxy)propyl 9,10-dioxo-9,10-dihydroanthracene-2-carboxylate
• Synonyms: 3-(4-(6-(tert-butyldiphenylsilyl-oxy)-2-hydroxy-2-methylhexyl)-phenoxy)propyl 9,10-dioxo-9,10-dihydroanthracene-2-carboxylate
• CAS NO: 942202-92-8
• Molecular Weight: 754.995
• Mol File: 942202-92-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(4-(6-(tert-butyldiphenylsilyl-oxy)-2-hydroxy-2-methylhexyl)-phenoxy)propyl 9,10-dioxo-9,10-dihydroanthracene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-(6-(tert-butyldiphenylsilyl-oxy)-2-hydroxy-2-methylhexyl)-phenoxy)propyl 9,10-dioxo-9,10-dihydroanthracene-2-carboxylate(942202-92-8)
• EPA Substance Registry System: 3-(4-(6-(tert-butyldiphenylsilyl-oxy)-2-hydroxy-2-methylhexyl)-phenoxy)propyl 9,10-dioxo-9,10-dihydroanthracene-2-carboxylate(942202-92-8)

Safety Data

• Hazardous Substances Data: 942202-92-8(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 117-78-2 anthraquinone-2-carboxylic acid 

Downstream Products

• 123171-29-9 6-(tert-butyldiphenylsilyloxy)hexan-2-one 

Relevant articles and documents

Intramolecular electron transfer initiated cation and radical formation through carbon-carbon bond activation

Radical cations can be formed in a spatially and temporally controlled manner by appending a sacrificial photooxidant to an easily oxidized substrate, leading to intramolecular electron transfer upon irradiation. The anthraquinone carboxyl group is an effective photooxidant that can promote single electron oxidation from an appended arene. The resulting intermediates undergo a cleavage reaction through carbon-carbon bond activation to provide either cations or radicals that react to form a range of products.