94225-18-0Relevant articles and documents
Synthesis of β-trimethylsilyl-β,γ-unsaturated ketones via Lewis acid promoted reactions of 2,3-bis(trimethylsilyl) propene with acid chlorides
Kang,U
, p. 1507 - 1512 (2007/10/02)
Reactions of 2,3-bis(trimethylsilyl)propene with acid chlorides in the presence of aluminum chloride give β-trimethylsilyl-β,γ-unsaturated ketones in high yields.
The reactivity of 3-bromo-2-trimethylsilyl-1-propene towards electrophiles. A short synthesis of 2-substituted-4-trimethylsilylfurans.
Knochel, P.,Normant, J.F.
, p. 4383 - 4386 (2007/10/02)
3-bromo-2-trimethylsilyl-1-propene 1c reacts with various electrophiles (aldehydes, a ketone, nitriles, terminal alkynes) in the presence of zinc to give functionnalized vinylsilanes.A three steps synthesis of 2-substituted-4-trimethylsilylfurans from 1c
