94227-23-3Relevant academic research and scientific papers
Perchlorocoronene: a Novel Host Precursor
Baird, Thomas,Gall, James H.,MacNicol, David D.,Mallinson, Paul R.,Michie, C. Ronald
, p. 1471 - 1473 (1988)
The title compound (1b), a new non-planar chlorocarbon possessing approximate D3d symmetry, has been prepared by chlorination of coronene (1a); complete substitution of (1b) by arenethiolate nucleophiles in the dipolar aprotic solvent DMEU (1,3-dimethylimidazolidin-2-one) yields the dodecathioethers (2a) and (2b), members of a new prospective host series.
Persulfurated Coronene: A New Generation of “Sulflower”
Dong, Renhao,Pfeffermann, Martin,Skidin, Dmitry,Wang, Faxing,Fu, Yubin,Narita, Akimitsu,Tommasini, Matteo,Moresco, Francesca,Cuniberti, Gianaurelio,Berger, Reinhard,Müllen, Klaus,Feng, Xinliang
, p. 2168 - 2171 (2017)
We report the first synthesis of a persulfurated polycyclic aromatic hydrocarbon (PAH) as a next-generation “sulflower.” In this novel PAH, disulfide units establish an all-sulfur periphery around a coronene core. The structure, electronic properties, and redox behavior were investigated by microscopic, spectroscopic and electrochemical methods and supported by density functional theory. The sulfur-rich character of persulfurated coronene renders it a promising cathode material for lithium-sulfur batteries, displaying a high capacity of 520 mAh g-1 after 120 cycles at 0.6 C with a high-capacity retention of 90%.
