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191-07-1

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191-07-1 Usage

Description

Coronene, also known as a polycyclic aromatic hydrocarbon, is an orthoand peri-fused polycyclic arene consisting of six peri-fused benzene rings. It is characterized by its yellow to gold fibrous powder appearance and is found in smoked fish. Studies have been conducted to examine its potential toxic and carcinogenic effects.

Uses

Used in Electronics Industry:
Coronene is used as an ultraviolet phosphor for charge-coupled devices (CCDs), contributing to the advancement of electronic technology and improving the performance of these devices.
Used in Superconductor Synthesis:
In the field of material science, Coronene is utilized to synthesize MBE-grown layered superconductors. Its unique chemical properties make it a valuable component in the development of superconducting materials, which have various applications in energy transmission, magnetic levitation, and other advanced technologies.
Used in Food Industry (Smoked Fish):
Coronene is also found in smoked fish, where it may have implications for the taste, aroma, or potential health effects of the product. Further research is needed to understand its role in the food industry and any potential impact on human health.

Carcinogenicity

An initiation–promotion assay in mice gave positive results; a repeated application gave negative results. On the basis of these studies, the working group concluded that these data were inadequate to permit an evaluation of the carcinogenicity of coronene to experimental animals.

Purification Methods

Crystallise coronene from *benzene or toluene, then sublime it in a vacuum. [Beilstein 5 III 2651.]

Check Digit Verification of cas no

The CAS Registry Mumber 191-07-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,9 and 1 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 191-07:
(5*1)+(4*9)+(3*1)+(2*0)+(1*7)=51
51 % 10 = 1
So 191-07-1 is a valid CAS Registry Number.
InChI:InChI=1/C24H12/c1-2-14-5-6-16-9-11-18-12-10-17-8-7-15-4-3-13(1)19-20(14)22(16)24(18)23(17)21(15)19/h1-12H

191-07-1 Well-known Company Product Price

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  • Aldrich

  • (335355)  Coronene  purified by sublimation, 99%

  • 191-07-1

  • 335355-100MG

  • 2,359.89CNY

  • Detail
  • Aldrich

  • (335355)  Coronene  purified by sublimation, 99%

  • 191-07-1

  • 335355-500MG

  • 8,424.00CNY

  • Detail
  • Aldrich

  • (C84801)  Coronene  97%

  • 191-07-1

  • C84801-100MG

  • 938.34CNY

  • Detail
  • Aldrich

  • (C84801)  Coronene  97%

  • 191-07-1

  • C84801-500MG

  • 3,229.20CNY

  • Detail

191-07-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name coronene

1.2 Other means of identification

Product number -
Other names EINECS 205-881-7

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:191-07-1 SDS

191-07-1Synthetic route

9,10-dihydro-9,10-di(penta-1,4-diyn-3-ylidene)anthracene
681164-24-9

9,10-dihydro-9,10-di(penta-1,4-diyn-3-ylidene)anthracene

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With TpRuPPh3(CH3CN)PF6 In 1,2-dichloro-ethane at 80℃; for 36h;86%
With ammonium hexafluorophosphate; [dichloro(p-cymene)(triphenylphosphane)ruthenium(II)] In 1,2-dichloro-ethane at 75℃; for 17h;8 mg
7-benzoperyleneacetaldehyde diethyl acetal

7-benzoperyleneacetaldehyde diethyl acetal

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With sulfuric acid In methanol for 0.5h; sonificated;82%
C32H36O4

C32H36O4

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With methanesulfonic acid In dichloromethane at -7 - 20℃; for 1.5h; Reagent/catalyst;80%
1,5,9-triethynyltriphenylene

1,5,9-triethynyltriphenylene

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With platinum(II) chloride In toluene for 12h; Schlenk technique; Inert atmosphere; Reflux;57%
propene
187737-37-7

propene

A

8-hydro-phenyl[bc]coronene
107716-56-3

8-hydro-phenyl[bc]coronene

B

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With KFI molecular sieve catalyst at 475℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;A 6%
B 11%
butan-1-ol
71-36-3

butan-1-ol

A

8-hydro-phenyl[bc]coronene
107716-56-3

8-hydro-phenyl[bc]coronene

B

8-methyl-8-hydro-phenyl[bc]coronene

8-methyl-8-hydro-phenyl[bc]coronene

C

7,8-dimethyl-8-hydro-phenyl[bc]coronene

7,8-dimethyl-8-hydro-phenyl[bc]coronene

D

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;A 4%
B 6%
C 6%
D 10%
propene
187737-37-7

propene

A

8-methyl-8-hydro-phenyl[bc]coronene

8-methyl-8-hydro-phenyl[bc]coronene

B

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With UZM-9 molecular sieve catalyst at 475℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;A 6%
B 10%
methanol
67-56-1

methanol

A

8-hydro-phenyl[bc]coronene
107716-56-3

8-hydro-phenyl[bc]coronene

B

8-methyl-8-hydro-phenyl[bc]coronene

8-methyl-8-hydro-phenyl[bc]coronene

C

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With DNL-6 molecular sieve microsphere catalyst at 500℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;A 8%
B 6%
C 6%
propan-1-ol
71-23-8

propan-1-ol

A

8-hydro-phenyl[bc]coronene
107716-56-3

8-hydro-phenyl[bc]coronene

B

8-methyl-8-hydro-phenyl[bc]coronene

8-methyl-8-hydro-phenyl[bc]coronene

C

7,8-dimethyl-8-hydro-phenyl[bc]coronene

7,8-dimethyl-8-hydro-phenyl[bc]coronene

D

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;A 4%
B 6%
C 6%
D 8%
pentan-1-ol
71-41-0

pentan-1-ol

A

8-hydro-phenyl[bc]coronene
107716-56-3

8-hydro-phenyl[bc]coronene

B

8-methyl-8-hydro-phenyl[bc]coronene

8-methyl-8-hydro-phenyl[bc]coronene

C

7,8-dimethyl-8-hydro-phenyl[bc]coronene

7,8-dimethyl-8-hydro-phenyl[bc]coronene

D

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;A 2%
B 6%
C 4%
D 8%
propene
187737-37-7

propene

A

8-hydro-phenyl[bc]coronene
107716-56-3

8-hydro-phenyl[bc]coronene

B

8-methyl-8-hydro-phenyl[bc]coronene

8-methyl-8-hydro-phenyl[bc]coronene

C

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With RHO molecular sieve catalyst at 525℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;A 8%
B 8%
C 6%
methanol
67-56-1

methanol

A

8-hydro-phenyl[bc]coronene
107716-56-3

8-hydro-phenyl[bc]coronene

B

8-methyl-8-hydro-phenyl[bc]coronene

8-methyl-8-hydro-phenyl[bc]coronene

C

7,8-dimethyl-8-hydro-phenyl[bc]coronene

7,8-dimethyl-8-hydro-phenyl[bc]coronene

D

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With DNL-6 molecular sieve microsphere catalyst In water at 475℃; under 750.075 Torr; for 1h; Reagent/catalyst; Temperature; Inert atmosphere;A 3%
B 6%
C 4%
D 7%
ethene
74-85-1

ethene

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With RHO molecular sieve catalyst at 475℃; under 750.075 Torr; for 1h; Inert atmosphere;6%
[2.2.2]paracyclophane
283-80-7

[2.2.2]paracyclophane

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With trimethyleneglycol at 380℃;
dibenzo[bc,kl]coronene
190-55-6

dibenzo[bc,kl]coronene

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With nitric acid at 220℃; Erhitzen des Reaktionsprodukts mit Natronkalk unter 20 mmHg Wasserstoff-Druck auf 500grad;
1,2-coronene-dione
88889-40-1

1,2-coronene-dione

A

naphth[2',1',8',7';4,10,5]anthra[1,9,8-cdef]chromen-2-one

naphth[2',1',8',7';4,10,5]anthra[1,9,8-cdef]chromen-2-one

B

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With lead(II) oxide under 12 Torr; im Luftstrom;
3,4-Coronen-dicarbonsaeure-anhydrid
4444-80-8

3,4-Coronen-dicarbonsaeure-anhydrid

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With soda lime at 400℃;
3,4-Coronen-dicarbonsaeure-anhydrid
4444-80-8

3,4-Coronen-dicarbonsaeure-anhydrid

A

bicoronenyl
56663-32-2

bicoronenyl

B

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With potassium hydroxide; nickel at 350℃;
coronene radical cation

coronene radical cation

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With [76]fullerene In dichloromethane Rate constant; Ambient temperature; also with C78;
polyethylene

polyethylene

A

anthranthrene
191-26-4

anthranthrene

B

1-methylene-1H-indene
2471-84-3

1-methylene-1H-indene

C

1-indene
95-13-6

1-indene

D

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With air at 800 - 900℃; Oxidation; Formation of xenobiotics;
waste tire

waste tire

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With air at 950℃; Oxidation; Formation of xenobiotics;
pulp and paper-generated biowaste

pulp and paper-generated biowaste

A

fluoranthene
206-44-0

fluoranthene

B

Benzo[ghi]perylene
191-24-2

Benzo[ghi]perylene

C

Retene
483-65-8

Retene

D

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With air at 976.85℃; Oxidation; Formation of xenobiotics;
9,12-dimethyl-dibenzo[c,g]phenanthrene-3,4-dicarboxylic acid-anhydride
7499-48-1

9,12-dimethyl-dibenzo[c,g]phenanthrene-3,4-dicarboxylic acid-anhydride

water
7732-18-5

water

potassium hydroxide

potassium hydroxide

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
at 320℃; eisernes Gefaess;
9.12-dimethyl-dibenzophenanthrene-carboxylic acid-(3)

9.12-dimethyl-dibenzophenanthrene-carboxylic acid-(3)

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With potassium hydroxide; water at 320℃;
9.12-dimethyl-dibenzophenanthrene-dicarboxylic acid-(3.4)-anhydride

9.12-dimethyl-dibenzophenanthrene-dicarboxylic acid-(3.4)-anhydride

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
With potassium hydroxide; water at 320℃;
[2.2.2]paracyclophane
283-80-7

[2.2.2]paracyclophane

PdO

PdO

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
at 380℃;
aluminium trichloride
7446-70-0

aluminium trichloride

1,4-di-(2,7)naphtha-cyclohexane
7130-24-7, 61849-91-0, 61849-92-1

1,4-di-(2,7)naphtha-cyclohexane

CS2

CS2

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
Erhitzen des Reaktionsprodukts mit Palladium auf 260grad;
tetracosahydro-coronene
54171-94-7

tetracosahydro-coronene

selenium

selenium

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
at 360℃; Dehydrierung;
9,12-dimethyl-dibenzo[c,g]phenanthrene-3-carboxylic acid

9,12-dimethyl-dibenzo[c,g]phenanthrene-3-carboxylic acid

water
7732-18-5

water

sodium hydroxide

sodium hydroxide

Coronene
191-07-1

Coronene

Conditions
ConditionsYield
at 320℃;
potassium hexafluorophosphate
17084-13-8

potassium hexafluorophosphate

cis-[Pt(II)(PEt)3(trifluoromethane-sulfonate)2]
165336-82-3

cis-[Pt(II)(PEt)3(trifluoromethane-sulfonate)2]

6Pt(2+)*12P(C2H5)3*4C3N3(C5H4N)3*12CF3SO3(1-)*2CH3COCH3=Pt6(P(C2H5)3)12(C3N3(C5H4N)3)4(CF3SO3)12*2CH3COCH3

6Pt(2+)*12P(C2H5)3*4C3N3(C5H4N)3*12CF3SO3(1-)*2CH3COCH3=Pt6(P(C2H5)3)12(C3N3(C5H4N)3)4(CF3SO3)12*2CH3COCH3

fumaric acid disodium salt
17013-01-3

fumaric acid disodium salt

Coronene
191-07-1

Coronene

6Pt(2+)*12P(C2H5)3*2C3N3(C5H4N)3*2C2H2(COO)2(2-)*C24H12*8PF6(1-)=Pt6(P(C2H5)3)12(C3N3(C5H4N)3)2(C4H2O4)2(PF6)8*C24H12

6Pt(2+)*12P(C2H5)3*2C3N3(C5H4N)3*2C2H2(COO)2(2-)*C24H12*8PF6(1-)=Pt6(P(C2H5)3)12(C3N3(C5H4N)3)2(C4H2O4)2(PF6)8*C24H12

Conditions
ConditionsYield
In [(2)H6]acetone; water; acetone to acetone soln. of triazine complex were added aq. soln. of carboxylate,coronene and aq. suspn. of platinum complex, sealed, immersed at 70°C for 1 h, solvent was removed, dried in vac., acetone-d6 was added, heated at 70°C for 1 h, aq. KPF6; elem. anal.;96%
C108H100Ir4N16(8+)*8CF3O3S(1-)

C108H100Ir4N16(8+)*8CF3O3S(1-)

Coronene
191-07-1

Coronene

C108H100Ir4N16(8+)*8CF3O3S(1-)*2C24H12

C108H100Ir4N16(8+)*8CF3O3S(1-)*2C24H12

Conditions
ConditionsYield
In methanol at 20℃; for 24h;95.5%
C108H100N16Rh4(8+)*8CF3O3S(1-)

C108H100N16Rh4(8+)*8CF3O3S(1-)

Coronene
191-07-1

Coronene

C108H100N16Rh4(8+)*8CF3O3S(1-)*2C24H12

C108H100N16Rh4(8+)*8CF3O3S(1-)*2C24H12

Conditions
ConditionsYield
In methanol at 20℃; for 24h;94.5%
C128H152Cl4Cu4N4O24Rh4(4+)*4CF3O3S(1-)

C128H152Cl4Cu4N4O24Rh4(4+)*4CF3O3S(1-)

Coronene
191-07-1

Coronene

C128H152Cl4Cu4N4O24Rh4(4+)*4CF3O3S(1-)*C24H12

C128H152Cl4Cu4N4O24Rh4(4+)*4CF3O3S(1-)*C24H12

Conditions
ConditionsYield
In methanol at 20℃; for 6h; Inert atmosphere; Schlenk technique;93.8%
Coronene
191-07-1

Coronene

1,2,3,4,5,6,7,8,9,10,11,12-dodecakischlorocoronene
94227-23-3

1,2,3,4,5,6,7,8,9,10,11,12-dodecakischlorocoronene

Conditions
ConditionsYield
With aluminum (III) chloride; Iodine monochloride In tetrachloromethane at 81℃; for 48h; Inert atmosphere; Schlenk technique;93%
With disulfur dichloride; aluminium trichloride; sulfuryl dichloride for 28h; Heating;90%
4,4'-bipyridine
553-26-4

4,4'-bipyridine

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

[Ag2(1,3-di(3-pyridyl)propane-1,3-dionato)2][OTf]2

[Ag2(1,3-di(3-pyridyl)propane-1,3-dionato)2][OTf]2

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

Coronene
191-07-1

Coronene

C112H112Ag4N12O8Rh4(8+)*8CF3O3S(1-)*2C24H12

C112H112Ag4N12O8Rh4(8+)*8CF3O3S(1-)*2C24H12

Conditions
ConditionsYield
Stage #1: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver trifluoromethanesulfonate In methanol at 20℃; for 6h; Darkness;
Stage #2: 4,4'-bipyridine; [Ag2(1,3-di(3-pyridyl)propane-1,3-dionato)2][OTf]2; Coronene at 20℃; for 24h;
89.6%
[Cp*Rh]2(4,4’-bis(dipyrromethane-5-yl)biphenyl)Cl2

[Cp*Rh]2(4,4’-bis(dipyrromethane-5-yl)biphenyl)Cl2

[Cu2(bddp)2]

[Cu2(bddp)2]

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

N,N′-dimethyl-1,4,5,8-naphthalenetetracarboxylic diimide
20958-66-1

N,N′-dimethyl-1,4,5,8-naphthalenetetracarboxylic diimide

Coronene
191-07-1

Coronene

2C30H20N4(2-)*4C10H15(1-)*4C19H23NO4(2-)*4Cu(2+)*4Rh(3+)*4CF3O3S(1-)*2C24H12*2C16H10N2O4

2C30H20N4(2-)*4C10H15(1-)*4C19H23NO4(2-)*4Cu(2+)*4Rh(3+)*4CF3O3S(1-)*2C24H12*2C16H10N2O4

Conditions
ConditionsYield
Stage #1: [Cp*Rh]2(4,4’-bis(dipyrromethane-5-yl)biphenyl)Cl2; silver trifluoromethanesulfonate In methanol at 20℃; for 6h; Darkness;
Stage #2: [Cu2(bddp)2] for 12h;
Stage #3: N,N′-dimethyl-1,4,5,8-naphthalenetetracarboxylic diimide; Coronene at 20℃; for 6h;
81.5%
2,4,6-tri(4-pyridyl)-1,3,5-triazine
42333-78-8

2,4,6-tri(4-pyridyl)-1,3,5-triazine

dichloro(μ-[6,11-di(hydroxy-κO)naphthacene-5,12-dionato(2-)-κO5:κO12])bis[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]diruthenium

dichloro(μ-[6,11-di(hydroxy-κO)naphthacene-5,12-dionato(2-)-κO5:κO12])bis[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]diruthenium

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

Coronene
191-07-1

Coronene

coronene.cntnd.[Ru2(p-cymene)2Cl2(6,11-dioxo-6,11-dihydronaphthacene-5,12-diolato)]3(2,4,6-tris(4-pyridyl)-1,3,5-triazine)(SO3CF3

coronene.cntnd.[Ru2(p-cymene)2Cl2(6,11-dioxo-6,11-dihydronaphthacene-5,12-diolato)]3(2,4,6-tris(4-pyridyl)-1,3,5-triazine)(SO3CF3

Conditions
ConditionsYield
In methanol to mixt. of Ru complex and Ag triflate in MeOH added triazine deriv. andcoronene; mixt. stirred at reflux for 24 h; filtered, solvent removed, residue dissolved in CH2Cl2, Et2O added for pptn.. solid filtered, dried under vac.; elem. anal.;81%
1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene
157131-39-0

1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene

(η6-p-cymRu)2(μ4-5,8-dihydroxy-1,4-naphthoquinone)Cl2

(η6-p-cymRu)2(μ4-5,8-dihydroxy-1,4-naphthoquinone)Cl2

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

Coronene
191-07-1

Coronene

[coronene*Ru6(p-cymene)6(1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene)2(μ-5,8-dioxido-1,4-naphthoquinonato)3][trifluoromethanesulfonate]6

[coronene*Ru6(p-cymene)6(1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene)2(μ-5,8-dioxido-1,4-naphthoquinonato)3][trifluoromethanesulfonate]6

Conditions
ConditionsYield
In methanol for 24h; Reflux;81%
Dichloromethyl methyl ether
4885-02-3

Dichloromethyl methyl ether

Coronene
191-07-1

Coronene

1-coronenecarboxaldehyde
22138-86-9

1-coronenecarboxaldehyde

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane; 1,2-dichloro-ethane at 20℃; for 19h;76%
2,4,6-tri(4-pyridyl)-1,3,5-triazine
42333-78-8

2,4,6-tri(4-pyridyl)-1,3,5-triazine

silever triflate

silever triflate

C30H41Cl2N2O2Ru2

C30H41Cl2N2O2Ru2

Coronene
191-07-1

Coronene

C24H12*C126H147N18O6Ru6(6+)*6CF3O3S(1-)

C24H12*C126H147N18O6Ru6(6+)*6CF3O3S(1-)

Conditions
ConditionsYield
Stage #1: silever triflate; C30H41Cl2N2O2Ru2 With air In dichloromethane at 20℃; for 2h;
Stage #2: 2,4,6-tri(4-pyridyl)-1,3,5-triazine; Coronene In dichloromethane at 20℃; for 48h;
75%
2,5-dimethoxy-7,7,8,8-tetracyano-p-quinodimethane
21003-99-6

2,5-dimethoxy-7,7,8,8-tetracyano-p-quinodimethane

Coronene
191-07-1

Coronene

(coronene)[(MeO)2TCNQ]

(coronene)[(MeO)2TCNQ]

Conditions
ConditionsYield
In dichloromethane72%
2,4,6-tri(4-pyridyl)-1,3,5-triazine
42333-78-8

2,4,6-tri(4-pyridyl)-1,3,5-triazine

[Ru2(η6-p-cymene)2(C6H2O4)Cl2]
1039768-31-4

[Ru2(η6-p-cymene)2(C6H2O4)Cl2]

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

Coronene
191-07-1

Coronene

coronene*[Ru6(p-cymene)6(2,4,6-tris(4-pyridyl)-1,3,5-triazine)2(2,5-dioxy-1,4-benzoquinonato)3](O3SCF3)6

coronene*[Ru6(p-cymene)6(2,4,6-tris(4-pyridyl)-1,3,5-triazine)2(2,5-dioxy-1,4-benzoquinonato)3](O3SCF3)6

Conditions
ConditionsYield
In methanol byproducts: AgCl; a mixt. of complex and Ag-salt in methanol was stirred at room temp. for2 h, filtered, triazine-compound and aromatic molecule were added, the mixt. was stirred at room temp. for 24 h; the solvent was removed under vac., the residue was taken up in CH2Cl2, filtered, concd., diethyl ether was added; elem. anal.;70%
1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene
157131-39-0

1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene

[Ru2(p-cymene)2(μ-9,10-dioxido-1,4-anthraquinonato)Cl2]
201941-87-9

[Ru2(p-cymene)2(μ-9,10-dioxido-1,4-anthraquinonato)Cl2]

silver trifluoromethanesulfonate
2923-28-6

silver trifluoromethanesulfonate

Coronene
191-07-1

Coronene

[coronene*Ru6(p-cymene)6(1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene)2(μ-9,10-dioxido-1,4-anthraquinonato)3][trifluoromethanesulfonate]6

[coronene*Ru6(p-cymene)6(1,3,5-tris{2-(pyridin-4-yl)-vinyl}benzene)2(μ-9,10-dioxido-1,4-anthraquinonato)3][trifluoromethanesulfonate]6

Conditions
ConditionsYield
In methanol for 24h; Reflux;66%
2,3,5,6-tetrafluoro-7,7',8,8'-tetracyanoquinodimethane
29261-33-4

2,3,5,6-tetrafluoro-7,7',8,8'-tetracyanoquinodimethane

Coronene
191-07-1

Coronene

(coronene)(F4TCNQ)

(coronene)(F4TCNQ)

Conditions
ConditionsYield
In dichloromethane66%
18-crown-6 ether
17455-13-9

18-crown-6 ether

rubidium

rubidium

Coronene
191-07-1

Coronene

[Rb(18-crown-6)][coronene]

[Rb(18-crown-6)][coronene]

Conditions
ConditionsYield
In tetrahydrofuran for 8h; Inert atmosphere; Schlenk technique;65%
7,7',8,8'-tetracyanoquinodimethane
1518-16-7

7,7',8,8'-tetracyanoquinodimethane

Coronene
191-07-1

Coronene

(coronene)3*TCNQ

(coronene)3*TCNQ

Conditions
ConditionsYield
In benzene for 12h;61%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

Coronene
191-07-1

Coronene

coronene

coronene

Conditions
ConditionsYield
Stage #1: 1,2-dimethoxyethane; Coronene With sodium at 20℃; for 8h; Inert atmosphere;
Stage #2: With Coarannulen In 1,2-dimethoxyethane; hexane at 10℃; for 48h; Inert atmosphere;
60%
6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-)

6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-)

Coronene
191-07-1

Coronene

6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-)*2C24H12

6C66H52N4Ni*4Fe(2+)*8C2F6NO4S2(1-)*2C24H12

Conditions
ConditionsYield
In [D3]acetonitrile at 20℃; for 1h;60%

191-07-1Relevant articles and documents

Gram scale synthesis of benzo[ghi]perylene and coronene

Van Dijk, Joost T. M.,Hartwijk, Astrid,Bleeker, Annemarie C.,Lugtenburg, Johan,Cornelisse, Jan

, p. 1136 - 1139 (1996)

-

-

Du Vernet et al.

, p. 1629 (1975)

-

Method for preparing coronene compound from non-cyclic olefin

-

Paragraph 0065-0068; 0071; 0072; 0075; 0076; 0083-0085, (2020/10/30)

The invention relates to a method for preparing a coronene compound from non-cyclic olefin. The method is characterized by comprising the following steps of: putting a reaction raw material into a reactor, and carrying out contact reaction with a catalyst containing an activated silicon-aluminum molecular sieve to obtain the coronene compound; wherein the reaction raw material comprises non-cyclicolefin. The method is mild in preparation condition, easy to operate and simple in process; the adopted raw material is low in cost and easy to obtain, therefore the method is suitable for large-scale production.

ORGANIC COMPOUND, THREE-DIMENSIONAL ORGANIC FRAMEWORK FORMED BY USING ORGANIC COMPOUND, SEPARATION SIEVE AND OPTICAL LAYER, WHICH COMPRISE ORGANIC FRAMEWORK, AND OPTICAL DEVICE COMPRISING OPTICAL LAYER AS OPTICAL AMPLIFICATION LAYER

-

Paragraph 0356; 0359; 0360; 0363; 0364, (2019/02/13)

An organic compound, a three-dimensional organic structure formed by using the organic compound, a separation sieve and an optical layer having the organic structure, and an optical device having the optical layer as an optical amplification layer are provided. The organic structure includes a plurality of organic molecules self-assembled by non-covalent bonding. Each of the unit organic molecules has an aromatic ring, a first pair of substituents being connected to immediately adjacent positions of substitutable positions of the aromatic ring, and a second pair of substituents being connected to immediately adjacent positions of remaining substitutable positions of the aromatic ring. The unit organic molecules are self-assembled by van der Waals interaction, London dispersion interaction or hydrogen bonding between the first and the second pairs of the substituents and by pi-pi interactions between the aromatic rings.

1, 5, 9-trisubstituted coronene compound and synthesis method thereof

-

Paragraph 0058; 0059; 0062; 0063, (2017/05/02)

The present invention relates to a 1, 5, 9-trisubstituted coronene compound and a synthesis method thereof. The structural formula of the compound is shown in img file = 'dest _ path _ image 001. TIF 'wi = '109 'he = '108', wherein R represents H, C1-C18 alkyl, phenyl, 4-methylphenyl, 4-methoxy phenyl, benzyl, cyclohexyl, 4-trifluoromethylphenyl, thiophene, furan and the like. According to the technical scheme of the invention, the easily prepared 1, 5, 9-triamido triphenylene is subjected to diazotization and halogenation reaction to obtain the tri-halogenated triphenylene. After that, the tri-halogenated triphenylene is subjected to Sonogashira reaction with various alkynes to generate atriyne-triphenylene compounds. Finally, through the metal-catalyzed reaction and the cyclization reaction under the effect of an organic base, various 1, 5, 9-trisubstituted coronene compounds, novel in structure, can be obtained. According to the technical scheme of the invention, raw materials are easy for mass preparation. Meanwhile, the synthesis step is relatively short and the operation is convenient. The obtained trisubstituted coronene compound is good in thermal stability and chemical stability, and the trisubstituted coronene emits the relatively strong fluorescence within the range of 420-550 nm according to the fluorescence emission spectrum of the trisubstituted coronene compound. Therefore, the trisubstituted coronene is an excellent fluorescent material for preparing UV ultraviolet charge-coupled devices (UV-CCD) and organic light-emitting diodes (OLEDs), and has a wide application prospect in the field of electronic materials.

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