94274-75-6

Upstream product

• 49833-38-7 (Z)-methyl 3-thiophenyl-2-propenoate 
• 709-27-3 (Z)-3-phenylsulfinylprop-2-enoic acid 
• 74-88-4 methyl iodide 
• 706-01-4 (2Z)-3-(phenylthio)acrylic acid 
• 186581-53-3 diazomethane 

Downstream Products

• 106446-26-8 (1S,2R,3S,4R)-3-Benzenesulfinyl-7-oxa-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester 
• 18910-47-9 9,10-dihydro-9,10-ethenoanthracene-12-carboxylic acid methyl ester 
• 106446-29-1 methyl (11R^*,12S^*)-12-phenylsulfonyl-9,10-dihydro-9,10-ethanoanthracene-11-carboxylate 
• 50363-84-3 (Z)-methyl 3-(4-methylphenyl)propenoate 
• 20754-20-5 3-p-tolyl-acrylic acid methyl ester 
• 49833-30-9 methyl (E)-3-phenylsulfinylprop-2-enoate 
• 55214-86-3 2-phenylsulfanyl-phenol 
• 49833-37-6 (E)-methyl 3-thiophenyl-2-propenoate 
• 13733-59-0 (E/Z)-methyl-3-(phenylthio) acrylate 
• 63068-63-3 (E)-3-Benzenesulfonyl-acrylic acid methyl ester 
• 106446-27-9 methyl exo-3-phenylsulfinyl-7-oxabicyclo<2.2.1>heptane-exo-2-carboxylate 
• 106446-27-9 methyl endo-3-phenylsulfinyl-7-oxabicyclo<2.2.1>heptane-endo-2-carboxylate 
• 19713-73-6 methyl (2Z)-3-phenylprop-2-enoate 

Relevant academic research and scientific papers

Reaction of Arynes with Vinyl Sulfoxides: Highly Stereospecific Synthesis of ortho-Sulfinylaryl Vinyl Ethers

The reaction of in situ generated arynes with aryl vinyl sulfoxides provides ortho-arylsulfinylaryl vinyl ethers via aryne σ-bond insertion into the S-O-bond and concomitant stereospecific S-O-vinyl migration. The cascade allows preparing di- or trisubsti

Effect of Catalyst and Solvent on the Stereochemistry of Diels-Alder Reactions Between Cyclopentadiene and 3-Phenylsulfinylprop-2-enoic Acids and Methyl Esters

In Diels-Alder reactions between cyclopentadiene and the isomeric 3-phenylsulfinylprop-2-enoic acids and methyl esters, greatest stereoselectivity (94percent d.e.) results when methyl (Z)-3-phenylsulfinylprop-2-enoate (7) and benzene solvent are used.The