942913-35-1Relevant academic research and scientific papers
DIVERGENT PATHWAYS OF REACTION BETWEEN CYCLOHEXANONE ENAMINES AND α,β-UNSATURATED ACID CHLORIDES
Butkus, Eugenius,Bielinyte-Williams, Birute
, p. 1343 - 1356 (1995)
The reaction of cyclohexanone enamines with α,β-unsaturated acid chlorides and 2- and 3-chloropropanoyl chlorides under various conditions has been investigated. α,α'-Annulation of enamines Ia-Ie occurs on treatment with chlorides IIa-IId or 3-chloropropanoyl chloride to give bicyclononane-2,9-dione derivatives III.The formation of isomeric bicyclononadiones IIIe and IIIh and chromanones VIIIa and VIIIb in the reaction of enamines derived from substituted cyclohexanones suggests that the cyclization might proceed also by another pathway than vis sigmatropic rearrangement.Based on the reaction course and product distribution in these reactions, a parallel reaction pathway involving a C-acylation-Michael addition has been suggested.
IMPROVEMENTS IN OR RELATED TO ORGANIC COMPOUNDS
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Page/Page column 10, (2008/06/13)
Malodour counteracting preparations for oral use comprising esterified fumarates of the formula (I) wherein X and Y have the same meaning as given in the description, is disclosed. Furthermore, the invention refers to a process for their preparation and t
