94319-63-8

Basic information

• Product Name: C₈H₁₀O₂S
• CAS NO: 94319-63-8
• Molecular Weight: 170.232
• Mol File: 94319-63-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₈H₁₀O₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₈H₁₀O₂S(94319-63-8)
• EPA Substance Registry System: C₈H₁₀O₂S(94319-63-8)

Safety Data

• Hazardous Substances Data: 94319-63-8(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 2365-48-2 Methyl thioglycolate 

Downstream Products

• 94319-61-6 2-(methylthiomethyl)cyclohex-2-en-1-one 
• 13694-36-5 2-benzyl-2-cyclohexenone 
• 94319-62-7 2-(prop-2-yn-1-yl) cyclohex-2-enone 
• 33553-25-2 2-(2-oxopropyl)cyclohex-2-en-1-one 
• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 38019-50-0 2-allyl-cyclohex-2-enone 
• 94340-40-6 (Z)-3-Ethoxy-4-(6-oxo-cyclohex-1-enyl)-but-2-enoic acid ethyl ester 

Relevant articles and documents

A bifunctional lewis acid induced cascade cyclization to the tricyclic core of ent-kaurenoids and its application to the formal synthesis of (±)-platensimycin

A mild and efficient bifunctional Lewis acid induced cascade cyclization reaction has been developed for construction of the tricyclic core of ent-kaurenoids. With ZnBr2 as the bifunctional Lewis acid, a series of substituted enones and dienes underwent cascade cyclization smoothly at room temperature and provided the tricyclic products in one pot with good yields (75-91%) and high diastereoselectivity. The cyclized product has been successfully employed for the formal synthesis of (±)-platensimycin.

2,3a,5,6,7,7a-HEXAHYDRO-3H,4H-BENZOTHIOPHENE-3,4-DIONE AND CYCLOPENTA-TETRAHYDROTHIOPHENE-3,4-DIONE ENOLATE ANIONS AS SYNTHETIC EQUIVALENTS TO CYCLOHEX-2-ENONE AND CYCLOPENT-2-ENONE C-2-CARBANIONS.

An efficient procedure for α-alkylation of cyclohex-2-enone and cyclopent-2-enone involving a base-promoted tandem of retrograde Dieckmann-Michael reactions of the C-alkylated derivatives of the title heterocycles is presented.