943249-30-7Relevant academic research and scientific papers
Chiral Pd-catalyzed enantioselective Friedel-Crafts reaction of indoles with γ,δ-unsaturated β-keto phosphonates
Kang, Young Ku,Kwon, Bo Kyung,Mang, Joo Yang,Kim, Dae Young
, p. 3247 - 3249 (2011)
The catalytic enantioselective Friedel-Crafts alkylation reaction promoted by chiral palladium complexes is described. The treatment of indoles with γ,δ-unsaturated β-keto phosphonates under the mild reaction conditions afforded the corresponding Friedel-
Catalytic enantioselective friedel-crafts alkylations of indoles with α′-phosphoric enones
Yang, Hyeyeon,Hong, Young-Taek,Kim, Sunggak
, p. 2281 - 2284 (2008/02/04)
The C2-symmetric bis(oxazoline) copper(II) complex proves to be an excellent catalyst in the Friedel-Crafts alkylation of indoles with α′-phosphoric enones. The enantioselectivities of this reaction are obtained in up to 98% ee.
