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IrH2(CH3CN)2(P(C6H5)3)2(1+)*SbF6(1-) = [IrH2(CH3CN)2(P(C6H5)3)2]SbF6 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

94345-85-4

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94345-85-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 94345-85-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,4,3,4 and 5 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 94345-85:
(7*9)+(6*4)+(5*3)+(4*4)+(3*5)+(2*8)+(1*5)=154
154 % 10 = 4
So 94345-85-4 is a valid CAS Registry Number.

94345-85-4Downstream Products

94345-85-4Relevant academic research and scientific papers

Arene and cyclohexadienyl complexes as intermediates in the selective catalytic dehydrogenation of cyclohexenes to arenes

Crabtree, Robert H.,Parnell, Charles P.

, p. 519 - 523 (1985)

A catalytic aromatization of cyclohexene to benzene is described by using [IrH2(Me2CO)2L2]SbF6 (L = PPh3) as catalyst in refluxing 1,2-C2H4Cl2. tert-Butylethylene (tbe) acts as hydrogen acceptor; in the absence of tbe, 2 equiv of cyclohexane are formed per mole of benzene. A mechanism is suggested based on the isolation of the proposed intermediates [Ir(η5-C6H7)HL2]SbF6 and [Ir(η6-C6H6)L2]SbF6. Some reactions of these complexes are discussed.

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