943540-11-2

Basic information

• Product Name: [Tl(η6-toluene)Au(pentachlorophenyl)2]
• CAS NO: 943540-11-2
• Molecular Weight: 992.152
• Mol File: 943540-11-2.mol

Chemical Properties

• CAS DataBase Reference: [Tl(η6-toluene)Au(pentachlorophenyl)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Tl(η6-toluene)Au(pentachlorophenyl)2](943540-11-2)
• EPA Substance Registry System: [Tl(η6-toluene)Au(pentachlorophenyl)2](943540-11-2)

Safety Data

• Hazardous Substances Data: 943540-11-2(Hazardous Substances Data)

Upstream product

• 60969-19-9 thallium(I) hexafluorophosphate 
• 108-88-3 toluene 

Relevant articles and documents

Photophysical studies and excited-state structure of a blue phosphorescent gold-thallium complex

The dinuclear complex {[TI(η6-toluene)][Au(C 6Cl5)2]} (1) displays very intense blue phosphorescence and a rigidochromic behavior in the solid state. The photophysical measurements in a glassy solution display an oligomerization process via metal-metal interactions. Density functional theory calculations show a distortion of the aurate-thallium T shape in the lowest triplet excited state, leading to a triplet metal-to-metal charge-transfer state.