943901-45-9Relevant articles and documents
Highly regioselective allylic substitution reactions catalyzed by an air-stable (π-Allyl)iridium complex derived from dinaphthocyclooctatetraene and a phosphoramidite ligand
Ye, Ke-Yin,Zhao, Zhuo-An,Lai, Zeng-Wei,Dai, Li-Xin,You, Shu-Li
, p. 2109 - 2114 (2013/08/23)
An air-stable (π-allyl)iridium complex derived from dinaphthocyclooctatetraene and a phosphoramidite ligand has been synthesized and found to be highly efficient in iridium-catalyzed allylic substitution reactions. This catalyst features excellent regiose
Iridium-catalyzed allylic substitutions with cyclometalated phosphoramidite complexes bearing a dibenzocyclooctatetraene ligand: Preparation of (π-Allyl)Ir complexes and computational and NMR spectroscopic studies
Raskatov, Jevgenij A.,Jaekel, Mascha,Straub, Bernd F.,Rominger, Frank,Helmchen, Guenter
, p. 14314 - 14328 (2013/01/15)
(π-Allyl)Ir complexes derived from dibenzocyclooctatetraene and phosphoramidites by cyclometalation are effective catalysts for allylic substitution reactions of linear monosubstituted allylic carbonates. These catalysts provide exceptionally high degrees
Enantioselective Iridium-catalyzed allylic alkylations - Improvements and applications based on salt-free reaction conditions
Gnamm, Christian,F?rster, Sebastian,Miller, Nicole,Br?dner, Kerstin,Helmchen, Günter
, p. 790 - 794 (2007/12/29)
Simplified procedures for the Ir-catalyzed asymmetric allylic alkylation reaction are described that often allow substitution products to be obtained with ≥99% ee. Applications to syntheses of important chiral building blocks, such as the Taniguchi lacton