94398-13-7Relevant academic research and scientific papers
NATURE OF THYOXYALLYL INTERMEDIATE IN THE DECOMPOSITION OF ALLENE EPISULFIDE AND PYRAZOLINE-4-THIONE
Furuhata, Toshiya,Ando, Wataru
, p. 5301 - 5308 (1986)
Thermolysis of tetramethylallene episulfide (10) gave 2,4-dimethyl-3-mercaptopenta-1,3-diene(12) via thioxyallyl intermediate(13) by unimolecular C-S bond cleavage. 3,3,5,5-Tetramethylpyrazoline-4-thione(11) also gave 12 probably via the same intermediate(13), which has a biradical character.
