NATURE OF THYOXYALLYL INTERMEDIATE IN THE DECOMPOSITION OF ALLENE EPISULFIDE AND PYRAZOLINE-4-THIONE

DOI: 10.1016/S0040-4020(01)82079-2

Source and publish data:

Tetrahedron p. 5301 - 5308 (1986)

Update date:2022-08-03

Topics:

Authors:

Furuhata, Toshiya

Ando, Wataru

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)82079-2

Thermolysis of tetramethylallene episulfide (10) gave 2,4-dimethyl-3-mercaptopenta-1,3-diene(12) via thioxyallyl intermediate(13) by unimolecular C-S bond cleavage. 3,3,5,5-Tetramethylpyrazoline-4-thione(11) also gave 12 probably via the same intermediate(13), which has a biradical character.

Full text of DOI:10.1016/S0040-4020(01)82079-2

Products guided by the article

Product name:Methanone, phenyl[tetrahydro-4,4-dimethyl-5-(1-methylethylidene)-2-phenyl-3-thienyl ]-, trans-

Cas No:94398-13-7

R&D Labs maybe for 94398-13-7

Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Clearsynth Labs Limited

Contact:+91 - 22 - 26355700

Address:17, Lotus Business Park, Andheri West
jiangsu senxuan pharmaceutical and chemical co.,ltd

Contact:86-523-87982810

Address:hongqiao industrial zone,taixing,jiangsu china
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:4009982989

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
SHANGHAI BIOSUNDRUG CO.,LTD.

Contact:86-21-34622192，13917187091，21-34622765

Address:No. 500 Caobao Road Shanghai P.R China

Relevant to this article

Theoretical evidence for pyramidalized bicyclic serine enolates in highly diastereoselective alkylations

Doi:10.1002/chem.200601746
(2007)
Regioselective mo-catalyzed hydrostannations as key steps in the synthesis of functionalized amino alcohols and heterocycles

Doi:10.1002/ejoc.200700126
(2007)
Nucleosides from Carbohydrate Adducts of Diaminomaleonitrile. A Novel Synthesis of 5-Amino-1-(β-D-ribofuranosyl)imidazole-4-carboxamide and 5-Amino-1-(β-D-ribopyranosyl)imidazole-4-carboxamide

Doi:10.1021/jo00206a004
(1985)
Oxidation kinetics of an antiasthmatic, 2-[(4-hydroxyphenyl)amino]-5-methoxybenzenemethanol, and stabilization with ascorbic acid

Doi:10.1002/jps.2600791014
(1990)
Efficient sonochemical protocol for the facile synthesis of dipyrimido-dihydropyridine and pyrimido[4,5-d]pyrimidines in aqueous β-cyclodextrin

Doi:10.1080/00397911.2017.1390685
(2018)
Bromination of 3-substituted benzo[b]thiophenes: Access to Raloxifen intermediate

Doi:10.1016/j.tetlet.2011.05.043
(2011)

Article Doi