944335-23-3Relevant academic research and scientific papers
Asymmetric synthesis of (R)-(-)-rhododendrol, the aglycone of the hepatoprotective agent rhododendrin
Sabitha, Gowravaram,Thirupathaiah,Yadav
, p. 1683 - 1688 (2007)
Starting from 2,3-O-isopropylidene-D-glyceraldehyde (3) as chiral material, (R)-(-)-rhododendrol 2, the aglycone of the naturally occurring rhododendrin 1 was synthesized. Copyright Taylor & Francis Group, LLC.
Stereoselective total synthesis of phenolic nonadecanediol
Chinnababu, Baggu,Purushotham Reddy, Sudina,Venkatesham, Kunuru,Chandra Rao, Dasireddi,Venkateswarlu, Yenamandra
, p. 613 - 618 (2014/06/09)
A simple and highly efficient synthetic route has been developed for synthesis of 1-(4-hydroxyphenyl)nonadecane-3,5-diol (1). The two stereogenic centers were generated by employing proline asymmetric α-hydroxylation (MacMillan α-hydroxylation), Jacobsen's hydrolytic kinetic resolution (HKR), and, finally, Yamaguchi oxirane opening as key steps (Scheme 2). Copyright
An efficient approach to the stereoselective synthesis of 2,6-disubstituted dihydropyrans via stannyl-Prins cyclization
Dziedzic, Magdalena,Furman, Bart?omiej
, p. 678 - 681 (2008/09/16)
A general method has been developed for the stereoselective construction of 2,6-disubstituted dihydropyrans based on the Lewis acid-catalyzed intramolecular reactions of oxocarbenium ions with vinylstannanes. This novel methodology was applied to the enan
