944335-80-2Relevant academic research and scientific papers
A new approach for the construction of a highly congested bicyclic system in polycyclic polyprenylated acylphloroglucinols (PPAPs)
Shimizu, Yohei,Kuramochi, Akiyoshi,Usuda, Hiroyuki,Kanai, Motomu,Shibasaki, Masakatsu
, p. 4173 - 4177 (2007)
A highly congested bicyclo[3.3.1]nonanone core of polycyclic polyprenylated acylphloroglucinols was constructed using a stereoselective Claisen rearrangement and an intramolecular aldol reaction as the key steps. The stereochemistry of C-4 appeared to con
