94438-56-9

Basic information

• Product Name: S-(n-dodecyl) 4-bromobenzothioate
• Synonyms: S-(n-dodecyl) 4-bromobenzothioate
• CAS NO: 94438-56-9
• Molecular Weight: 385.409
• Mol File: 94438-56-9.mol

Chemical Properties

• CAS DataBase Reference: S-(n-dodecyl) 4-bromobenzothioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-(n-dodecyl) 4-bromobenzothioate(94438-56-9)
• EPA Substance Registry System: S-(n-dodecyl) 4-bromobenzothioate(94438-56-9)

Safety Data

• Hazardous Substances Data: 94438-56-9(Hazardous Substances Data)

Upstream product

• 2757-37-1 didodecyl disulfide 
• 106-38-7 para-bromotoluene 
• 1122-91-4 4-bromo-benzaldehyde 
• 112-55-0 1-dodecylthiol 
• 102315-51-5 4-Brom-ω-n-dodecylmercapto-acetophenon 
• 94754-21-9 ω-Azido-ω-dodecylmercapto-4-brom-acetophenon 

Relevant articles and documents

Visible-Light-Mediated Cross Dehydrogenative Coupling of Thiols with Aldehydes: Metal-Free Synthesis of Thioesters at Room Temperature

Thioesters play a crucial role in biological systems and serve as important building blocks for organic synthesis. Herein, Eosin Y and TBHP mediated photochemical cross dehydrogenative coupling (PCDC) between feedstock aldehydes and thiols has been descri

Microwave-assisted Synthesis of Thioesters from Aldehydes and Thiols in Water

We describe the synthesis of thioesters via copper- or iron-catalyzed coupling of thiols with aldehydes on application of microwave irradiation. In this protocol, a variety of aliphatic and aromatic aldehydes and thiols were used, and the products were ob

Metal-free sp3 C-H functionalization: A novel approach for the syntheses of selenide ethers and thioesters from methyl arenes

A DTBP-promoted metal-free and solvent-free formation of C-Se and C-S bonds through sp3 C-H functionalization of methyl arenes with diselenides and disulfides is described. the Partner Organisations 2014.

Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions

A DTBP-promoted C-H thiolation of aldehydes with disulfides under metal-free and solvent-free conditions is described. The system shows good functional group tolerance to afford thioesters in moderate to excellent yields. the Partner Organisations 2014.

Iron-catalyzed synthesis of thioesters from thiols and aldehydes in water

The preparation of thioesters through the iron-catalyzed coupling reaction of thiols with aldehydes is described. The reactions were carried out by using tert-butyl hydroperoxide (TBHP) as an oxidant and water as a solvent in most cases. This system is co

Synthesis of thioesters through copper-catalyzed coupling of aldehydes with thiols in water

Copper-catalyzed C-S bond formation between aldehydes and thiols in the presence of TBHP as an oxidant is described. Functional groups including chloro, trifluoromethyl, bromo, iodo, nitrile, ester and thiophene are all tolerated by the reaction condition