944722-06-9Relevant academic research and scientific papers
Rhodium(I)-catalyzed synthesis of indoles: Amino-claisen rearrangement of N-propargylanilines
Saito, Akio,Oda, Shoko,Fukaya, Haruhiko,Hanzawa, Yuji
supporting information; experimental part, p. 1517 - 1524 (2009/07/17)
Mild and facile preparations of 2-substituted or 2,3-disubstituted indole compounds were achieved by RhH(CO)(Ph3P)3 (4-10 mol %)-catalyzed reaction of N-propargylanilines in hexafluoroisopropyl alcohol (HFIP). The formation of indole
Synthesis of 2,3-disubstituted indoles by a rhodium-catalyzed aromatic amino-claisen rearrangement of N-propargyl anilines
Saito, Akio,Kanno, Ayumi,Hanzawa, Yuji
, p. 3931 - 3933 (2008/03/11)
(Chemical Equation Presented) Give me a ring! A cationic RhI catalyst promotes the formation of fused arenes containing a five-membered ring (see scheme) by an aromatic amino-Claisen rearrangement of N-propargyl aniline derivatives in refluxing
