944913-68-2

Upstream product

• 37081-58-6 (1R,2S,4R,5S)-2,4-dimethyl-8-oxa-bicyclo[3.2.1]oct-6-en-3-one 
• 96691-93-9 (1R,2R,3r,4S,5S)-2,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-ol 
• 100-42-5 styrene 
• 944913-67-1 C₁₇H₂₂O₃ 

Downstream Products

• 944913-69-3 C₂₅H₃₂O₃ 
• 944913-73-9 C₂₄H₄₄O₅Si 
• 944913-72-8 C₂₇H₃₆O₃ 
• 944913-71-7 C₃₀H₄₃O₇P 
• 944913-70-6 C₂₆H₃₄O₄ 

Relevant academic research and scientific papers

Chiral N-heterocyclic carbenes in natural product synthesis: Application of Ru-catalyzed asymmetric ring-opening/cross-metathesis and Cu-catalyzed allylic alkylation to total synthesis of baconipyrone C

(Chemical Equation Presented) Chiral carbenes as major players: Two recently discovered chiral N-heterocyclic carbene (NHC) complexes play a crucial role in a concise enantioselective total synthesis of baconipyrone C (see scheme). An (NHC)Cu complex catalyzes a double asymmetric allylic alkylation (AAA), and an (NHC)Ru complex catalyzes an asymmetric ring-opening/cross- metathesis (AROM/CM) to establish the absolute configuration of the target. RCM = ring-closing metathesis.