944940-90-3Relevant articles and documents
Highly catalytically active high-spin single-atom iron catalyst supported by catechol-containing microporous 2D polymer
Cao, Rui,Gu, Defa,Hong, Song,Li, Guangwen,Liu, Yushan,Liu, Yuzhou
, p. 1240 - 1244 (2020)
Traditionally, Fe-SACs are prepared through energy-intense processes, which often lead to the loss of precision in structural features from the starting substrates and impeding rational design. We herein described the synthesis of a unique catechol-containing porous polymer with designed features in the substrates maintained, affording atomically dispersed iron catalyst (Fe-SAC) through treatment of ferrous chloride (FeCl2). An aberration-corrected scanning transmission electron microscope (AC-STEM) and synchrotron X-ray absorption spectroscopy (XAS) were employed to shed light on the local coordination geometry of the atomically dispersed iron catalyst. The resulting Fe-SAC exhibits excellent catalytic performance in reduction of nitroaromatics with highest molar Kapp among all Fe based catalysts.
Emission color-tunable oxazol(in)yl-substituted excited-state intramolecular proton transfer (ESIPT)-based luminophores
Bigall, Nadja C.,Duvinage, Daniel,G?bel, Dominik,Nachtsheim, Boris J.,Rusch, Pascal
supporting information, p. 15430 - 15433 (2020/12/25)
Oxazolinyl- and arylchalcogenazolyl-substituted hydroxyfluorenes exhibiting excited-state intramolecular proton transfer (ESIPT) are described as potent and highly modular luminophores. Emission color tuning was achieved by varying the π-expansion and the
Novel 9,9-dimethylfluorene-bridged D-π-A-type fluorophores with a hybridized local and charge-transfer excited state for deep-blue electroluminescence with CIEy ~ 0.05
Qiu, Xu,Ying, Shian,Wang, Cong,Hanif, Muddasir,Xu, Yuwei,Li, Ya,Zhao, Ruiyang,Hu, Dehua,Ma, Dongge,Ma, Yuguang
, p. 592 - 600 (2019/01/24)
Deep-blue light emitting materials are of great significance in the fields of commercial full-color organic light-emitting diodes (OLEDs) and solid-state lighting. The hybridized local and charge-transfer excited state (HLCT) is a promising strategy to ac