94536-96-6

Upstream product

• 94493-15-9 (2R,6S)-6-((R)-2,3-Dimethoxy-propyl)-5,5-dimethyl-4-trimethylsilanyloxy-5,6-dihydro-2H-pyran-2-carbonitrile 
• 94493-15-9 (2R,6S)-6-((S)-2,3-Dimethoxy-propyl)-5,5-dimethyl-4-trimethylsilanyloxy-5,6-dihydro-2H-pyran-2-carbonitrile 
• 94493-14-8 (2R,6S)-6-((S)-2,3-Dimethoxy-propyl)-5,5-dimethyl-4-oxo-tetrahydro-pyran-2-carbonitrile 
• 94493-12-6 (S)-6-((S)-2,3-Dimethoxy-propyl)-4-methoxy-5,5-dimethyl-5,6-dihydro-pyran-2-one 
• 94493-10-4 (R)-6-((R)-2,3-Dimethoxy-propyl)-5,5-dimethyl-dihydro-pyran-2,4-dione 
• 129156-04-3 (2R,4S,6S)-6-((S)-2,3-Dimethoxy-propyl)-4-hydroxy-5,5-dimethyl-tetrahydro-pyran-2-carbonitrile 
• 94493-13-7 (R)-2-((R)-2,3-Dimethoxy-propyl)-3,3-dimethyl-2,3-dihydro-pyran-4-one 
• 94493-14-8 (2R,6S)-6-((R)-2,3-Dimethoxy-propyl)-5,5-dimethyl-4-oxo-tetrahydro-pyran-2-carbonitrile 
• 94493-12-6 (S)-6-((R)-2,3-Dimethoxy-propyl)-4-methoxy-5,5-dimethyl-5,6-dihydro-pyran-2-one 
• 94493-10-4 (R)-6-((S)-2,3-Dimethoxy-propyl)-5,5-dimethyl-dihydro-pyran-2,4-dione 
• 94493-13-7 (R)-2-((S)-2,3-Dimethoxy-propyl)-3,3-dimethyl-2,3-dihydro-pyran-4-one 
• 94493-07-9 4-Hydroxy-6,7-dimethoxy-3,3-dimethyl-heptan-2-one 
• 94536-95-5 (+/-)-3,4-dimethoxybutanal 
• 94493-08-0 C₁₂H₂₁ClO₅ 

Downstream Products

• 104432-05-5 C₄₅H₅₇NO₁₁Se 
• 73787-25-4 Benzoic acid (2R,4R,6S)-2-((S)-2,3-dimethoxy-propyl)-6-methoxycarbonimidoyl-3,3-dimethyl-tetrahydro-pyran-4-yl ester 

Relevant academic research and scientific papers

Synthetic Approaches to Pederin. A Synthesis of (+/-)-Benzoylpedamide

A Lewis acid-catalysed addition of Me3SiCN to a 4-oxo-3,4-dihydro-2H-pyran is a key step in the synthesis of (+/-)-benzoylpedamide (2).

Studies related to the synthesis of pederin. Part 2. Synthesis of pederol dibenzoate and benzoylpedamide

Syntheses of the ring B fragments (+)-pederol dibenzoate (2) and (±)-benzoylpedamide (3) of the insect toxin pederin (1) are described. An intramolecular directed aldol condensation was used to construct the tetrahydropyran ring in (+)-pederol dibenzoate