945534-61-2

Upstream product

• 108-24-7 acetic anhydride 
• 945534-58-7 (3R,4S,5S,6E)-1-[(tert-butyl)-dimethylsilyloxy]-3,5-dimethyl-4-((1'R)-1'-phenylethoxy)oct-6-en-2-one 
• 945534-59-8 (2S,4S,5R,7R,8S,9S,10E)-1-benzyloxy-5-[(tert-butyl)-dimethylsilyloxy]-2-methoxy-4-hydroxy-7,9-dimethyl-8-((1'R)-1'-phenylethoxy)dodec-10-en-6-one 
• 945534-60-1 (2R,3R,4S,5S,6R,1'R,2'S,4'S)-2-{1'-(tert-butyl-dimethylsilyloxy)-2'-hydroxy-5'-benzyloxy-4'-methoxy-pentyl}-4-((R)-1-phenylethoxy)-6-allyl-2-hydroxy-3,5-dimethyl-2,3,5,6-tetrahydro-4H-pyran 

Downstream Products

• 945534-62-3 (2R,3R,4S,5S,6R,1'R,2'S,4'S)-2-[1',2'-diacetoxy-5'-benzyloxy-4'-methoxy-pentyl]-4-triethylsilyloxy-6-allyl-2-methoxy-3,5-dimethyl-2,3,5,6-tetrahydro-4H-pyran 
• 795290-06-1 (2R,3R,4S,5S,6R,1'R,2'S,4'S,2''R)-2-[1',2'-diacetoxy-5'-benzyloxy-4'-methoxy-pentyl]-4-triethylsilyloxy-6-[2''-hydroxy-3''-methoxypropyl]-2-methoxy-3,5-dimethyl-2,3,5,6-tetrahydro-4H-pyran 

Relevant academic research and scientific papers

Short synthesis of the C16-C28 polyketide fragment of apoptolidin A aglycone

Starting from (E,E)-1-[(1R)-(phenylethyl)oxy]-2-methylpenta-1,3-diene and triethylsilyl enol ether of butanone rapid access to Koert's advanced C 10-C28 polyketide fragment of apoptolidin A is now possible. The Royal Society of Chemi