94575-69-6Relevant academic research and scientific papers
O-(p-Methoxyphenylethynyl)phenyl Glycosides: Versatile New Glycosylation Donors for the Highly Efficient Construction of Glycosidic Linkages
Hu, Yang,Yu, Ke,Shi, Li-Li,Liu, Lei,Sui, Jing-Jing,Liu, De-Yong,Xiong, Bin,Sun, Jian-Song
supporting information, p. 12736 - 12744 (2017/09/25)
A novel alkyne-activation-based glycosylation protocol using o-(p-methoxyphenylethynyl)phenyl (MPEP) glycoside was established. The glycosyl MPEP donors were shelf-stable and could be prepared efficiently via Sonogashira reaction from the corresponding o-
O-acetylphenol ether glycosylation donor and preparation method and application thereof
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Paragraph 0043-0045, (2017/09/02)
The invention discloses an O-acetylphenol ether glycosylation donor, a preparation method thereof and application of the O-acetylphenol ether glycosylation donor in a glycosylation reaction. The O-acetylphenol ether glycosylation donor is stable, easy to store and widely used in various glycosylation reactions; the leaving group of the donor is the phenolic ether protecting group, and differing from operation of a benzyl ether protecting group, operation of phenolic ether protecting group can be conducted. The glycosylation reaction condition is mild, and all donors sensitive to acids and electrophilic reagents can accept the condition.
