74808-17-6Relevant articles and documents
Phenyliodine bis(trifluoroacetate) (PIFA) as an excellent promoter of 2-deoxy-2-phthalimido-1-thioglycosides in the presence of triflic acid in glycosylation reactions
Kajimoto, Tetsuya,Morimoto, Koji,Ogawa, Ryosuke,Dohi, Toshifumi,Kita, Yasuyuki
, p. 2138 - 2142 (2015)
A combination of phenyliodine bis(trifluoroacetate) (PIFA) and trifluoromethanesulfonic acid was found to be an effective activator for the glycosylation reaction, of which the glycosyl donor was p-(octyloxy)phenyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido
MPTGs: Thioglycoside Donors for Acid-Catalyzed O-Glycosylation and Latent-Active Synthetic Strategies
Du, Shaofu,Ragains, Justin R.
supporting information, p. 980 - 983 (2019/02/05)
4-(p-Methoxyphenyl)-4-pentenylthioglycosides (MPTGs) undergo acid-catalyzed O-glycosylation with a range of alcohol acceptors in the presence of 10 mol % of triflic acid at room temperature. Particularly encouraging is the reactivity of MPTGs toward unrea
O-acetylphenol ether glycosylation donor and preparation method and application thereof
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Paragraph 0128-0130, (2017/09/02)
The invention discloses an O-acetylphenol ether glycosylation donor, a preparation method thereof and application of the O-acetylphenol ether glycosylation donor in a glycosylation reaction. The O-acetylphenol ether glycosylation donor is stable, easy to store and widely used in various glycosylation reactions; the leaving group of the donor is the phenolic ether protecting group, and differing from operation of a benzyl ether protecting group, operation of phenolic ether protecting group can be conducted. The glycosylation reaction condition is mild, and all donors sensitive to acids and electrophilic reagents can accept the condition.