946005-73-8Relevant articles and documents
A New Compound for Sequential Sensing of Picric Acid and Aliphatic Amines: Physicochemical Details and Construction of Molecular Logic Gates
Ghosh, Ashutosh,Seth, Sourav Kanti,Ghosh, Arnab,Pattanayak, Pradip,Mallick, Arabinda,Purkayastha, Pradipta
, p. 1157 - 1164 (2021/05/05)
Picric acid (PA) at low concentration is a serious water pollutant. Alongside, aliphatic amines (AAs) add to the queue to pollute surface water. Plenty of reports are available to sense PA with an ultralow limit of detection (LOD). However, only a handful of works are testified to detect AAs. A new fluorescent donor-acceptor compound has been synthesized with inherent intramolecular charge transfer (ICT) character that enables selective and sensitive colorimetric quantitative detection of PA and AAs with low LODs in non-aqueous as well as aqueous solutions. The synthesized compound is based on a hemicyanine skeleton containing two pyridenylmethylamino groups at the donor and a benzothiazole moiety at the acceptor ends. The detailed mechanisms and reaction dynamics are explained spectroscopically along with computational support. The fluorescence property of the detecting compound changes due to protonation of its pyridinyl centers by PA leading to quenching of fluorescence and subsequently de-protonation by AAs to revive the signal. We have further designed logic circuits from the acquired optical responses by sequential interactions.
Colorimetric indicators for specific recognition of Cu2+ and Hg2+ in physiological media: Effect of variations of signaling unit on optical response
Dey, Nilanjan,Kumari, Namita,Biswakarma, Dipen,Jha, Satadru,Bhattacharya, Santanu
, p. 50 - 57 (2018/12/11)
Easy to synthesize probes are designed using bispicolyl moiety as the receptor unit with two different signaling moieties, anthraquinone and bisindolyl. Both the compounds show ‘naked-eye’ sensing of Cu2+ and Hg2+ in ~100% aqueous me
Di(2-methylpyridine)amine modified pyrene derivative fluorescence probe, and synthetic method and applications thereof
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, (2017/09/26)
The invention discloses a di(2-methylpyridine)amine modified pyrene derivative fluorescence probe, and a synthetic method and applications thereof. The structure of the di(2-methylpyridine)amine modified pyrene derivative fluorescence probe is disclosed i