946408-99-7

Basic information

• Product Name: (2R)-1-tert-butyldiphenylsilyloxy-2-methyl-hexane
• Synonyms: (2R)-1-tert-butyldiphenylsilyloxy-2-methyl-hexane
• CAS NO: 946408-99-7
• Molecular Weight: 354.608
• Mol File: 946408-99-7.mol

Chemical Properties

• CAS DataBase Reference: (2R)-1-tert-butyldiphenylsilyloxy-2-methyl-hexane(CAS DataBase Reference)
• NIST Chemistry Reference: (2R)-1-tert-butyldiphenylsilyloxy-2-methyl-hexane(946408-99-7)
• EPA Substance Registry System: (2R)-1-tert-butyldiphenylsilyloxy-2-methyl-hexane(946408-99-7)

Safety Data

• Hazardous Substances Data: 946408-99-7(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 946409-00-3 C₂₃H₃₄SiO₂ 

Downstream Products

• 624-22-6 (2S)-2-methyl-1-hexanol 
• 66050-98-4 (2R)-methyl-1-hexanol 

Relevant articles and documents

Fully reagent-controlled asymmetric synthesis of (-)-Spongidepsin via the Zr-catalyzed asymmetric carboalumination of alkenes (ZACA reaction)

The ZACA reaction has been shown to proceed satisfactorily with internally OH-substituted 1-alkenes, provided that the OH group is unprotected and non-allylic. This reaction was used for reagent-controlled asymmetric construction of 3. Allylic alcohol was