66050-98-4

Basic information

• Product Name: 1-Hexanol, 2-methyl-, (R)-
• CAS NO: 66050-98-4
• Molecular Formula: C7H16O
• Molecular Weight: 116.203
• Mol File: 66050-98-4.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: 1-Hexanol, 2-methyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Hexanol, 2-methyl-, (R)-(66050-98-4)
• EPA Substance Registry System: 1-Hexanol, 2-methyl-, (R)-(66050-98-4)

Safety Data

• Hazardous Substances Data: 66050-98-4(Hazardous Substances Data)

Upstream product

• 131906-75-7 (S)-2-Methylhexyl Tetrahydropyranyl Ether 
• 946408-99-7 (2R)-1-tert-butyldiphenylsilyloxy-2-methyl-hexane 
• 2612-26-2 2-butylpropane-1,3-diol 
• 592-41-6 1-hexene 
• 201230-82-2 carbon monoxide 
• 41692-46-0 ethyl 2-methylhexanoate 
• 141022-82-4 (S)-(+)-4-isopropyl-3-hexanoyl-2-oxazolidinone 
• 946409-00-3 C₂₃H₃₄SiO₂ 
• 617-86-7 triethylsilane 
• 775-12-2 diphenylsilane 
• 91177-72-9 (2S,3R)-heptane-2,3-diol 
• 75-24-1 trimethylaluminum 
• 296241-81-1 (4R,5R)-2-((1S,2R)-2-Butyl-cyclopropyl)-4,5-bis-(methoxy-diphenyl-methyl)-[1,3,2]dioxaborolane 
• 4536-23-6 2-methylhexanoic acid 

Downstream Products

• 1116651-79-6 (4S,5R)-4-methyl-2-((R)-2-methylhexylselanyl)-5-phenyl-4,5-dihydrooxazole 
• 66050-82-6 (2R)-methylhexyl (S)-α-methoxy-α-trifluoromethylphenylacetate 
• 99824-63-2 (R)-2-methylhexyl 4-methylbenzenesulfonate 
• 99833-15-5 (S)-2-methylhexyl 4-methylbenzenesulfonate 
• 97424-48-1 (S)-1-bromo-2-methylhexane 
• 1337552-55-2 C₃₉H₇₄O₅Si₂ 
• 1337552-82-5 C₃₆H₇₀O₅Si₂ 
• 1337552-81-4 C₃₆H₆₈O₅Si₂ 
• 1337552-79-0 C₄₂H₈₂O₅Si₃ 

Relevant articles and documents

Synthesis and Absolute Configuration of Natural 2-Pyrones

2-Pyrones are frequently produced by microorganisms and often exhibit interesting bioactivities. Therefore, a short and easy synthetic access to these natural products is desirable. Synthetic routes to nectriapyrone, gibepyrone A, racemic gulypyrone A, (+)-germicidin C, (ent)-desoxygermicidin C and (ent)-prolipyrone A via a modular approach are presented, allowing the assignment of the absolute configurations of the latter three chiral compounds. The method failed for the synthesis of (ent)-phomapyrone B that was thus synthesized via a different route, resulting in an assignment of the absolute configuration of natural phomapyrone B.

Advances and Setbacks in the Total Synthesis of the Fungal Metabolite Curvicollide C: Synthesis and Elaboration of Non-Aldol Stereotriads from Gosteli-Type Allyl Vinyl Ethers

Advances and setbacks are reported in regard to the asymmetric total synthesis of the fungal metabolite curvicollide C relying on a synthetic strategy that exploits non-aldol stereotriads as chiral building blocks. A catalytic asymmetric Gosteli-Claisen rearrangement, a two-step aldehyde-to-alkyne-homologation, and a Julia-Kocienski olefination served as key C/C-connecting transformations.

Stereochemical investigations reveal the mechanism of the bacterial activation of n-alkanes without oxygen

Anaerobic growth of the bacterium strain HxN1 with n-hexane gives nearly equal amounts of (2R,1 R)- and (2S,1 R)-(1-methylpentyl)succinate, which are formed by the radical addition of the hydrocarbon to fumarate (see scheme). The highly selective attack on the pro-S hydrogen atom at C2 of n-hexane is associated with inversion of the configuration at C2 during binding to fumarate and exhibits isotopic discrimination against a C-2H bond. Copyright