946416-33-7

Upstream product

• 946416-32-6 1,5-anhydro-2,3,4,6-tetra-O-benzyl-1,2-C-(dibromomethylene)-α-D-glycero-D-galacto-hexitol 
• 124-41-4 sodium methylate 
• 4132-26-7 2,3,4,6-tetra-O-benzyl 1,5-anhydro-D-arabino-hex-1-enitol 

Downstream Products

• 946416-34-8 methyl 2-deoxy-3,4,5,7-tetra-O-benzyl-α-D-arabino-hept-2-enoseptanoside 
• 1383956-18-0 methyl 2-deoxy-2-C-phenyl-3,4,5,7-tetra-O-benzyl-α-D-arabino-hept-2-enoseptanoside 
• 1383956-17-9 methyl 2-deoxy-2-C-(2-phenylallyl)-3,4,5,7-tetra-O-benzyl-α-D-arabino-hept-2-enoseptanoside 
• 1383956-21-5 methyl 2-deoxy-2-C-(2-phenylethynyl)-3,4,5,7-tetra-O-benzyl-α-D-arabino-hept-2-enoseptanoside 
• 1383956-19-1 methyl 2-deoxy-2-C-(p-methoxyphenyl)-3,4,5,7-tetra-O-benzyl-α-D-arabino-hept-2-enoseptanoside 
• 1383956-20-4 methyl 2-deoxy-2-C-(m-tolyl)-3,4,5,7-tetra-O-benzyl-α-D-arabino-hept-2-enoseptanoside 
• 1383956-22-6 methyl 2-deoxy-2-C-(octyn-1-yl)-3,4,5,7-tetra-O-benzyl-α-D-arabino-hept-2-enoseptanoside 
• 946416-36-0 methyl 4,5,7-tri-O-benzyl-α-D-glycero-D-talo-septanoside 
• 946416-35-9 methyl 4,5,7-tri-O-benzyl-α-D-manno-sept-3-uloside 

Relevant academic research and scientific papers

Branching out at C-2 of septanosides. Synthesis of 2-deoxy-2-C-alkyl/aryl septanosides from a bromo-oxepine

This paper deals with the synthesis of 2-deoxy-2-C-alkyl/aryl septanosides. A range of such septanoside derivatives was synthesized by using a common bromo-oxepine intermediate, involving C-C bond forming organometallic reactions. Unsaturated, sevenmember

Synthesis of septanosides through an oxyglycal route

(Chemical Equation Presented) A new route to synthesize septanoside derivatives from protected 2-hydroxyglycals is reported. Ring expansion of a pyranoside to a septanoside was achieved through key reactions of a cyclopropanation, ring opening, oxidation,