946532-54-3Relevant academic research and scientific papers
A new type of heteroleptic complex of divalent lead and synthesis of the P-plumbyleniophosphasilene, R2Si=P-Pb(L): (L = β-diketiminate)
Yao, Shenglai,Block, Stefan,Brym, Markus,Driess, Matthias
, p. 3844 - 3846 (2008/03/13)
The synthesis and structures of the first heteroleptic β-diketiminato complexes of lead(ii) with terminal phenolato, bis(trimethylsilyl)amido, bis(trimethylsilyl)phosphanido and silylidenephosphanido ligands are reported; 207Pb NMR spectroscopic data indicate that lead(ii) can serve as a σ-donor or acceptor centre, depending on the electronegativity of the terminal ligand. The Royal Society of Chemistry.
