94751-56-1Relevant academic research and scientific papers
Novel and convenient to substituted imidazoles
Chang, Yu-An,Chang, Hsiang
experimental part, p. 1235 - 1238 (2010/03/03)
(Chemical Equation Presented) A one-pot synthesis of imidazoles has been established from the addition of azides to 2-amidoacrylates, and this synthetic method demonstrates an efficient synthesis of imidazole-4-carboxylates.
Biosynthesis of Sulfur Compounds. Investigations of the Biosinthesis of Asparagusic Acid.
Parry, Ronald J.,Mizusawa, A.E.,Chiu, I.C.,Naidu, M.V.,Ricciardone, M.
, p. 2512 - 2521 (2007/10/02)
Investigations of the biosynthesis of the naturally occuring 1,2-dithiolane asparagusic acid (1) in Asparagus officinalis have shovn that the substance is derived from inobutyric acid via the intermediacy of methacrylic acid, 2-methyl-3-mercaptopropionic acid, and S-(2-carboxy-n-propyl) cysteine.The conversion of isobutyric acid to methacrylic acid in Asparagus has also been shown to proceed by oxidation of the 2-pro-S methyl group of isobutyrate.Finally, the absolute configuration of naturally occuring S-(2-carboxy-n-propyl)cysteine has been determined.
